Carbohydrates Flashcards
Give the main example of a hexose monosaccharide
Glucose
What is a hexose monosaccharide
A carbohydrate with 6 carbon atoms in it
Give an example of a pentose monosaccharide
Ribose
What is a pentose monosaccharide
A carbohydrate with 5 carbon atoms in it
Give three examples of hexose monosaccharides
Glucose
Fructose
Galactose
What is the general formula for a monosaccharide?
CnH2nOn
What is the chemical formula of glucose?
C6H12O6
What is meant by the type of sugar?
How many carbon atoms are present. e.g. hexose or pentose
Name the two isomers of glucose
- Alpha glucose
- Beta glucose
What is an isomer?
A molecule with the same molecular formula but a structural formula and arrangement of atoms
What is the structural difference between alpha and beta glucose?
The OH group on carbon one is orinetated the opposite way around
In aplha the OH group is attatched below the plane of the ring where as in beta glucose the OH group is attatched above the plane of the ring
What type of sugar is glucose?
A hexose monosaccharide
Glucose is a polar molecule
TRUE or FLASE
True
Glucose is a polar molecule this means that is it [blank] in water
fill in the blank
Glucose is a polar molecule this means that it is soluble in water
Why is glucose soluble in water?
The OH groups form hydrogen bonds with water molecules, allowing it to be dissolved in water
All monosaccharides are polar and therefore soluble in water
TRUE or FALSE?
TRUE
Why is it important that glucose can dissolve in water
It means that glucose can be dissolved in the cytosol of the cell
What is the definition of a disaccharide?
Sugars formed from two monosaccharides joined together by a condensation reaction
What is formed when alpha-glucose reacts with alpha-glucose?
Maltose
Which type of glucose forms maltose-
alpha or beta
Alpha glucose
What is formed when alpha-glucose reacts with fructose?
Sucrose
What is formed when alpha-glucose reacts with galactose?
Lactose
What type of bond is formed between two alpha-glucose molecules to form the disaccharide maltose?
1, 4 glycosidic bonds
Which two monosaccharides form the disaccharide maltose?
Alpha glucose + Alpha glucose
Which two monosaccharides form the disaccharide sucrose?
Alpha glucose + Fructose
Which two monosaccharides form the disaccharide lactose?
Alpha glucose + Galactose
Give three examples of polysaccharides
- Starch
- Cellulose
- Glycogen
Name the polysaccharides formed form alpha glucose
Starch
glycogen
What is a glycosidic bond?
A covalent bond formed between two monosaccharides in a condensation reaction
What type of reaction breaks apart disaccharides and polysaccharides to form monosaccharides?
Hydrolisis reaction
What is a polysaccharide?
A sugar formed form 10 or more monosaccharides joined together by glycosidic bonds in a condensation reaction
monosaccharides and disaccharides are s[blank] and s[blank]
fill in the blanks
Monosaccharides and disaccharides are sweet and soluble
they are SUGARS
Polysaccharides are NOT [blank]
fill in the blank
Polysaccharides are NOT sugars
Why are polysaccharides insoluble?
They are large in size
Which glucose isomer is present in amylose?
alpha glucose
Name the two types of starch
Amylose
Amylopectin
Which isomer of glucose is in glycogen?
Alpha glucose
Which isomer of glucose is in amylopectin?
Alpha-glucose
Which isomer of glucose is in cellulose?
Beta glucose
Describe the bonding that occurs in amylose?
1,4 glycosidic bonding between alpha glucose molecules
Describe the bonding that occurs in amylopectin?
1,4 and 1,6 glycosidic bonding between alpha glucose molecules
Describe the bonding that occurs in cellulose
1,4 glycosidic bond between beta glucose molecules
What is the structure of amylose
Alpha helix structure
What is the structure of amylopectin?
Branched structure
What is the structure of cellulose?
Straight chain molecule
What function does the helix/coiled structure of amylose provide?
Makes amylose compact, so a large amount can be stored in a small space
Draw the structure of alpha glucose
Drawn with OH facing below the ring on carbon 1
Draw the structure of beta glucose
Drawn with OH above the ring on carbon 1
Draw the structure of ribose
A pentose monosaccharide with all H-OH except on carbon 4which is CH2OH-H
and carbon 1 which is OH-H
Name the two types of starch
Amylose
Amylopectin
How does the large size of amylose relate to its function?
Makes amylose insoluble so it doesn’t affect the water potential of the cell
How does the fact that amylose is a polymer of glucose relate to its function
It means amylose stores a lot of glucose molecules which can be used in respiration to RELEASE energy
How does the large size of glycogen relate to its function?
It makes glucose insoluble so it does not affect the water potential of the cell
When does hydrolysis occur?
When plants/animals need energy
so they are releasing the individual monomers of glucose so that respiration can happen
How does the branched structure of glycogen relate to its function?
- The branched ends allow for hydrolysis to release glucose for respiration to release energy
- It creates flexibillity and more folding which means that it is more compact which means that a large amount can be stored in a small space which is good for storage
How does the fact that glycogen is a polymer of glucose relate to its function?
It means that glycogen can store a lot of glucose which is used in respiraiton for the release of energy
How does the large size of amylopectin relate to its function?
It makes it insoluble so that it doesn’t affect the water potential of the cell
How does the branched structure of amylopectin relate to its function?
- The branched ends allow for hydrolisis to release glucose molecules for respiration to release energy
- It allows for flexibility and folding which makes the molecules more compact which means that a large amount can be stored in a small space
How does the fact that amylopectin is a polymer of glucose relate to its function?
It means that it can store a lot of glucose molecules which are used in respiration for the release of energy
How do microfibrils of cellulose form?
Outwards facing OH groups form hydrogen bonds between chains of cellulose molecules to form microfibrils
In cellulose every alternate beta glucose molecule is facing upside down
TRUE or FALSE
TRUE
This is so that the condensation reaction can actually take place anda 1,4 glycosidic bond can be formed- this is the reason that some of the OH groups face outwards and H bond form between cellulose molecules to form microfibrils
How are macrofibrils of cellulose formed?
Microfibrils are held together by Hydrogen bonds to form macrofibrils
How does the insolubility of cellulose relate to its structure?
Makes cellulose stable
This means that its DOESN’T dissolve in water so its shape doesnt break or change, hence making it stable
How does the forming of microfibrils relate to the function of cellulose
- It gives cellulose a high tensile strength, which means that it does not burst when water moves in by osmosis
- It gives the plant turgidity and support
How does the fact that cellulose is made of beta glucose relate to its function
It makes cellulose very difficult to hydrolise
because the enzymes in animals can only easily hydrolise (break down) alpha glucose
Give the three structural features of amylose
- Large size
- Coiled/helix structre
- Polymer of glucose
Give the three structural features of amylopectin
- Large size
- Brached structure*
- Polymer of glucose
*this contributes TWO things to amylopectin’s structure
Glycogen is a [blank] version of amylopectin
fill in the blank
more branched
Give the three structural features of glycogen
- Large size
- Branched structure*
- Polymer of glucose
*this contributes TWO things to glycogen’s structure
Give the three structural features of cellulose
- Insoluble
- Forms microfibrils
- Polymer of beta glucose
Describe the bonding that occurs in glycogen
1,4 and 1,6 glycosidic bonding between alpha glucose monosaccharides
hydrolysis reactions [blank] bonds
fill in the blank
break
condensation reactions [blank] bonds
form
List the following in order of solubility
amlyopectin, ribose, glucose, amylose
for most to least
- Glucose
- Ribose
- Amylose
- Amylopectin
Name the carbohydrate molecule used to store energy in plants
Starch
including amylose & amylopectin