carbohydrates Flashcards

1
Q

what do carbohydrates function as, eg.
1. starch in plants / glycogen in animals
2. cellulose in plant cell wall / chitin in insects
3. infection + antibodies
4. intermediates / energy substrates

A
  1. an energy store
  2. structural
  3. cell recognition
  4. metabolism
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2
Q

what are monosaccharides

A

single sugars

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3
Q

what are oligosaccharides

A

2-10 (or 20) residues

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4
Q

what are polysaccharides

A

> 20 residues

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5
Q

how are monosaccharides are classified

A

according to the number of C atoms
and whether an aldehyde (aldose) or ketone (ketose)

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6
Q

give the general formula for glucose

A

C6H12O6

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7
Q

what are suffix endings for aldose

A

-ose

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8
Q

what is the suffix ending for ketose

A

-ulose

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9
Q

what is an epimer

A

different compounds with the same molecular formula that differ in configuration by only one carbon

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10
Q

how are epimers named

A

due to which carbon the change in configuration happens on
eg. C4 epimer

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11
Q

what does intramolecular mean

A

taking place within the same molecule
eg. hydroxyl group reacting with a carbonyl group

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12
Q

what does anomeric C mean

A

a carbon that is bonded to 2 oxygen atoms

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13
Q

how do you determine whether the sugar is alpha or beta
Give the acronym

A

if the -OH group is attached to the anomeric C1 below the ring = alpha
if the -OH group is attached to the anomeric C1 above the ring = beta
ABBA = Alpha Below Beta Above (the anomeric carbon)

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14
Q

what are alpha and beta structures called

A

anomers

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15
Q

what is the most abundant monosaccharide

A

aldose

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16
Q

what do aldoses have on carbon 1

A

an aldehyde group

17
Q

what do ketoses have on carbon 2

A

a keto group

18
Q

what does intermolecular mean

A

occurring between different molecules

19
Q

why type of carbon of one of the component monosaccharides is involved in glycosidic bonds

A

the anomeric C

20
Q

when is a dissacharide a reducing sugar

A

provided that the anomeric C from one of the component monosaccharides is not involved in the glycosidic bond