carbohydrates Flashcards

1
Q

where are carbohydrates produced

A

by photosynthesis

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2
Q

what are carbs oxidised to produce

A

CO2 and H2O and energy

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3
Q

what is a monosaccharide

A

the simplest carbohydrates, no hydrolysis occurs
3 to 6 carbon atoms
a carbonyl group
several hydroxide groups

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4
Q

what is disaccharide

A

two monosaccharide units

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5
Q

what is a polysaccharide

A

many monosaccharide units

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6
Q

what is an olagasaccharide

A

3 to 10 monosaccharide units

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7
Q

what is an aldose

A

monosaccharides with an aldehyde group, also have many hydroxyl group
(triose, tetrose, pentose, hexose)

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8
Q

what is a ketose

A

monosaccharides with a ketone group with many hydroxyl group

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9
Q

fischer projection

A

used to represent carbohydrates
most oxidised group goes at the top
chiral carbons at in the middle of the structure

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10
Q

whats the difference between a D-glyceraldehyde and an L- glyceraldehyde

A

L- hydroxyl group on the left of the chiral carbon
D- hydroxyl group on the right of the chiral carbon

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11
Q

what determines the L or D status of a glyceraldehyde

A

the hydroxyl group farthest away from the chiral carbon

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12
Q

what is an epimer

A

structures that differ at one chiral centre

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13
Q

galactosemia

A

when there is a lack of enzymes reuired for galactose metabolism, results in an accumulation of galactose intermediates which has toxic effects in the liver, brain, kidneys and eyes

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14
Q

are cyclic or linear monosaccarides more stable

A

cyclic

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15
Q

when are cyclic monosaccharides produced

A

when the hydroxyl group of C-5 reacts with the aldehyde group or ketone group

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16
Q

whats the differnce between an alpha-D-glucose and a beta-D-glucose

A

alpha-below the ring
beta- above the ring

17
Q

what happens when alpha-D-glucose or beta-D-glucose is in solution

A

clyclic structures open and close

18
Q

how to test for sugars (ex. glucose) in the blood

A

use fehlings solution to convert a glucose into a gluconate by reducing inorganic ions such as copper

19
Q

what is a reducing sugar

A

a sugar that will reduce inorganic ions such as Cu++
(ex. aldoses and ketoses)

20
Q

what is a glucose oxidase test

A

‘dip stick test’ quicker way to test for glucose in the urine

21
Q

whats the lifetime of red blood cells

A

120 days

22
Q

what is lactose made up from

A

disaccharide between glucose and galactose
found in milk and milk products

23
Q

what is a lactose intolerance

A

lack of lactase enzyme in small intestine which means lactose can pass onto the colon, bacteria start to ferment lactose causing stomach cramps and bloating

24
Q

what class of carbohydrate is glycogen

A

highly branched polysaccharide composed of multiple glucose units

25
Q

what does an alpha bond look like in glycogen

A

below the ring

26
Q

what is sucrose made up from

A

glucose and fructose

27
Q

what is maltose made up from

A

2 units of glucose

28
Q

what is starch

A

plant form of carbohydrate ingested by humans

29
Q

what is amylose

A

unbranched starch comprised of glucose units
hydrolysed by alpha-amylase secreted by salivary glands in the pancreas

30
Q

amylopectin

A

branched form of starch
hydrolysed by alpha-amylase secreted by salivary glands in the pancreas

31
Q

ratio of amylose and amylopectin in starch

A

20% amylose
80% amylopectin

32
Q

cellulose

A

storage in plants
contains a beta-1,4 linkage (above the ring)
mammals lack cellulases

33
Q
A