carbohydrates Flashcards
where are carbohydrates produced
by photosynthesis
what are carbs oxidised to produce
CO2 and H2O and energy
what is a monosaccharide
the simplest carbohydrates, no hydrolysis occurs
3 to 6 carbon atoms
a carbonyl group
several hydroxide groups
what is disaccharide
two monosaccharide units
what is a polysaccharide
many monosaccharide units
what is an olagasaccharide
3 to 10 monosaccharide units
what is an aldose
monosaccharides with an aldehyde group, also have many hydroxyl group
(triose, tetrose, pentose, hexose)
what is a ketose
monosaccharides with a ketone group with many hydroxyl group
fischer projection
used to represent carbohydrates
most oxidised group goes at the top
chiral carbons at in the middle of the structure
whats the difference between a D-glyceraldehyde and an L- glyceraldehyde
L- hydroxyl group on the left of the chiral carbon
D- hydroxyl group on the right of the chiral carbon
what determines the L or D status of a glyceraldehyde
the hydroxyl group farthest away from the chiral carbon
what is an epimer
structures that differ at one chiral centre
galactosemia
when there is a lack of enzymes reuired for galactose metabolism, results in an accumulation of galactose intermediates which has toxic effects in the liver, brain, kidneys and eyes
are cyclic or linear monosaccarides more stable
cyclic
when are cyclic monosaccharides produced
when the hydroxyl group of C-5 reacts with the aldehyde group or ketone group