C8- the rate and extent of chemical change 💥 Flashcards

1
Q

What is the rate of a chemical reaction ?

A
  • the rate of a chemical reaction, is the speed at which a chemical reaction takes place
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2
Q

How can the mean rate of reaction be calculated ?

Hint: quantity/time

A
  • the mean rate of reaction can be calculated, by using equation=
  • quantity of product formed ➗ time taken
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3
Q

In a reactant —> product graph, what does the slope of the line tell us ?

A
  • if the quantity of product against time is plotted, the slope of the line gives us an idea of the rate of reaction.
  • this is because, the sleeper the slope, the faster the reaction
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4
Q

In the reactant —> product graph, for the quantity of product formed against time, why does the graph get less steep ?

A
  • ; the slope of the line will gradually become less steep- telling is rate of the reaction is decreasing [the reaction is slowing down.]
  • this is because, a lot of the reactant molecules have already reacted, and turned into product- therefore, fewer reactant molecules are available to react.
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5
Q

In the reactant —> product graph, why is the slope of the line now zero, and the line is flat. [at the end]?

Hint: all the reactant molecules…

A
  • at the end, the slope of the line is now zero, and the line is flat.
  • this is because, at this point the reaction has stopped, since all of the reactant molecules have already reacted.
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6
Q

What are the units for the quantity of product formed ?

Hint: not a compound unit

A
  • the quantity of product formed is typically in grams
  • ; if our product is a gas, the quantity is then measured in cm^3
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7
Q

What does the reactant —> product graph, look like ?

A
  • the rate is initially fast; the reaction then slows down and the reaction finally stops
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8
Q

Define the term ‘collision theory ?’

Hint: how chemical reactions…

A
  • collision theory, is a scientific explanation of how chemical reactions occur.
  • ; collision theory also explains how various factors, can affect the rates of reactions
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9
Q

Explain the concept of collision theory

Hint: reacting particles…

A
  • collision theory states that: chemical reactions can only occur, when the reacting particles collide with each other.
  • This is because, the collisions must have sufficient energy
  • ; collision theory also states, the rate of a chemical reaction, is determined by the frequency of fruitful collisions [successful]
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10
Q

What do collision theory state, as the reason for a reaction between reactants ?

Hint: collisions

A
  • collision theory states that the reaction between reactants, is due to: the collisions of the reactants particles, and the energy they have when they collide
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11
Q

According to collision theory, why don’t all collisions lead to a reaction ?

Hint: minimum energy

A
  • not all collisions lead to a reaction because, they have a certain minimum energy known as the activation energy.
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12
Q
  • Fill in the gaps: Any change in __________ that increase: the number of collisions and the ______ of the particles, will increase the ____ of reaction.
A
  • Any change in conditions that increase: the number of collisions, and the number of the particles, will increase the rate of reaction.
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13
Q

Why are the five conditions [factors], that the rate of [chemical] reactions depend on ? [5]

Hint: catalyst

A
  • temperature
  • the concentration of liquids, and pressure of gases.
  • the surface area of solid reactants
  • and, the presence or absence of a catalyst
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14
Q

What does frequency mean ?

Hint: number

A
  • frequency, is the number of successful collisions, per second
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15
Q

Explain the effect of surface area, on rate of reaction

Hint: collision theory

A
  • collision theory states, that the reaction between reactants is due to: the collisions of the particles of the reactants, and the energy they have when they collide is needed
  • so increasing the surface area, exposes more solid particles to the other reactant
  • this then increases the frequency of successful collisions [of the reactants’ particles]- and therefore, the rate of reaction increases.
  • This is because, if surface area increases—> more particles are available to react——> more successful collisions——> and the rate of reaction increases.
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16
Q

How is surface area: volume ratio affect rate of reaction

Hint: smaller size blocks of solid rectant

A
  • smaller sized blocks of solid reactant, have a greater surface area: volume ratio than larger blocks
  • meaning that smaller sidled blocks of solid reactant, have more particles on the surface- meaning there are more collisions per second [per unit time]
  • and, this increases rate of reaction
17
Q

How can the surface area of a solid reactant be increased ?

A
  • the surface area of a solid reactant can be increased, by:
  • breaking it up into very small pieces, and decreasing the particle size
18
Q

State the units for rate of reaction ?

Hint:

A
  • the units for rate of reaction, are: g/s , cm^3/s and mol/s
19
Q

Explain how there can be different units, for measuring rate of reaction

A
  • there can be different units for rate of reaction, depending on whether volume or mass, is being measured
  • This is because, the mass of a solid product is often measured in grams; the volume of a gaseous product, is often measured in cm^3
20
Q

Why is there more than one unit, for rate of reaction ?

A
  • there’s more than one unit, for rate of reaction because:
  • if a gas was being given off during a reaction, you could: take some measurements, and then work out the volume being given off per second, at any particular time during the reaction.
  • ; rate usually measured, by looking at how fast the concentration of one of the reactants is falling at any one time.
21
Q

Explain why many collisions, don’t lead to a chemical reaction

A
  • many collisions don’t lead to a chemical reaction because:
  • the particles may not collide with enough energy or in the correct orientation
  • This is because, the particles need to be moving towards in each other, and facing each other- so they don’t simply bounce off each other, which would result in an unsuccessful collision.
22
Q
  • Fill in the gaps: if _______ area increases—> more __________ are available to react——> more successful collisions——> and the rate of reaction ________.
A

This is because, if surface area increases—> more particles are available to react——> more successful collisions——> and the rate of reaction increases.

23
Q

How can you remember, how temperature affects rate of reaction ?

A
  • temperature
  • speed
  • number of collisions
  • energy
  • greater than Ea
  • chance of successful collisions
24
Q

How can you remember, how pressure affects rate of reaction ?

A
  • pressure
  • pushes and squashes
  • successful collisions
25
Q

How can you remember, how concentration affects rate of reaction ?

A
  • concentration of reactants in solution
  • more particles available
  • more frequent