C8 - Rates of Reaction Flashcards
What is the general equation for reversible reactions?
A + B ⇌ C + D
What is the balanced symbol equation for the Haber process?
N2 + 3H2 ⇌ 2NH3
What is 2NH3?
ammonia
What can we uses ammonia for?
nitrogen based fertilisers
What is a source of nitrogen?
can be extracted from air
What is a source of hydrogen?
produced by reacting methane with steam
How is ammonia formed?
Purified nitrogen & hydrogen passed over iron catalyst at around 450° & 200 ATM pressure
How can we increase the yield of ammonia?
cool it down & convert to a liquid which is removed
What happens to the mixture of unreacted gases (hydrogen & nitrogen) ?
recycled back over catalyst
What is the symbol indicating a reversible reaction?
⇌
What happens if you heat hydrated copper sulfate (blue) ?
reacts & forms anhydrous copper sulfate (white) & produces water
What happens if a reversible reaction happens in a closed system? What is this called?
causes the forwards & backwards reactions to happen at exactly the same rate = dynamic equilibrium
What is the equation for rates of reaction?
chnge in reactnt (or prdct)/ time
What is Le Chatelier’s principle?
position equillbrm. will shift to oppose external changes
What is the effect of increasing the concentration of reactants on a reaction at dynamic equillibrium?
favours forwards reaction
What is the effect of decreasing the concentration of products on a reaction at dynamic equillibrium?
favours forwards reaction
What is the effect of increasing pressure on a reaction at dynamic equillibrium?
favours reaction that leads to fewst. molecules
What is the effect of decreasing pressure on a reaction at dynamic equillibrium?
favours reaction that leads to mst molecules
What is the effect of increasing temperature on a reaction at dynamic equillibrium?
favours endo. reaction
What is effect of decreasing temperature on a reaction at dynamic equillibrium?
favours exo. reaction
What 2 things must particles have to react?
actvtn enrgy & collisions
If you increase the temperature of a reaction, how does it affect the RoR?
- ↑ RoR
- particles gain thrml enrgy
- more particles have actvtn enrgy
- move faster & have more frqunt cllsns
If you increase the concentration, how does it affect the RoR?
- ↑ RoR
- more particles there are in crtn volume = more frquntly particles will collide
If you increase the surface area, how does it affect the RoR?
- ↑ RoR
- more reactant particles are exposed = more frqunt collisions
How do catalysts affect RoR?
- ↑ RoR
- reduces actvtn enrgy
- finds altnrtv pthwy for reaction to take requiring less enrgy
If you increase the pressure, how does this affect the RoR?
- ↑ RoR
- more GAS particles in certain volume = more frquntly GAS particles will collide