c5 - rates of reaction Flashcards

1
Q

equilibrium

A

a state in a reaction where the rate of the forward reaction is equal to the rate of the reverse reaction

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2
Q

le chatelier’s principle

A

if a system is at equilibrium and a change is made to any of the conditions then the system responds to counteract that change

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3
Q

dynamic equilibrium

A

where forward and backward reactions are happening at the same rate

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4
Q

effect of increasing temperature on equilibrium

A

shifts equilibrium to favour endothermic reaction

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5
Q

effect of decreasing temperature on equilibrium

A

shifts equilibrium to favour the exothermic reaction

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6
Q

effect of increase of concentration of reactants in a reaction (3)

A

equilibrium shifts to right to make more product bringing it back to equilibrium

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7
Q

effect of increasing concentration of products in a reaction (3)

A

equilibrium shifts to left to make more product bringing it back to equilibrium

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8
Q

effect of increasing pressure of gas in reaction

A

equilibrium shifts to favour the reaction with less particles as this will decrease the pressure

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9
Q

effect of decreasing pressure of gas in a reaction

A

equilibrium shifts to favour the reaction with most particles as this will decrease the pressure

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10
Q

activation energy

A

minimum energy required for a chemical reaction to take place

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11
Q

collision theory

A

the theory states that for a chemical reaction to happen particles must collide with sufficient energy

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12
Q

frequency

A

the amount of times something happens in a second

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13
Q

concentration

A

number of particles in a given volume

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14
Q

factors effecting rate of reaction

A
  • temperature
  • pressure
  • concentration of solution
  • surface area
  • presence of a catalyst
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15
Q

in reference to collision theory

what two things does rate of reaction depend on

A
  • frequency of collisions between particles
  • the energy with which the particles collide
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16
Q

what is the relationship between concentration and rate of reaction

A

directly proportional , if u double concentration u double the rate

17
Q

collision theory in reference to temperature (3)

A

when u increse temperature the particles will move faster causing more frequent succesful collisions between particles. speed also causes particles to collide with more energy meaning activation energy is likely exceeded

18
Q

collision theory in reference to concentration

A

if concentration is incresed there are more particles in a given volume causing more frequent succesful collisions causing rate of reaction to increase as it is directly proportional to concentration

19
Q

collision theory

collision theory in reference to surface area

A

when you increase the surface area of a solid u increase the number of particles available for collision causing there to be more frequent succesful collisions increasing the rate of reaction

20
Q

collision theory in reference to pressure

A

when pressure is increased in a gaseous reaction the rate will increase as there are more particles in a given volume of gas causing more frequent successful collisions

21
Q

mean rate of reaction formula

A

quantity of reactant used / time taken
or
quantity of product formed / time taken

22
Q

units for rate of reaction

A

The units of rate of reaction may be given as g/s, cm3/s or mol/s.

23
Q

how do you calculate specific rate of reaction

A

Draw a tangent at the specific time and calculate the gradient.

24
Q

define reversible reactions in terms of energy changes

A

If a reversible reaction is exothermic in one direction, it is endothermic in the opposite direction. The same amount of energy is transferred in each case.