C2 - The Periodic Table Flashcards

1
Q

What is the Periodic Table of Elements?

A

The Periodic Table of Elements is a table where elements are arranged based on chemical properties.

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3
Q

What are the vertical columns in the periodic table called?

A

Groups

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4
Q

What are the horizontal rows in the periodic table called?

A

Periods - each period has the same number of shells. The further periods you go, the bigger the size of the positive nuclear charge.

E.g:

  • period 1 = 1 shell (2)
  • period 2 = 2 shells (2.8)
  • period 3 = 3 shells (2.8.8)
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7
Q

Who are the 3 scientists that were involved in the development of the Periodic Table? What was each of their developments?

A

John Dalton (also linked to History of the Atom) - arranged elements into order of their atomic weights

John Newlands - produced law of octaves (properties of every eighth element seemed similar) - he left no room for new elements

Dmitri Mendeleev - solved the problem around atomic number by leaving gaps for new elements (and predicting their new properties based on the elements next to the gap) - he produced the periodic table we know today.

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8
Q

What determines an elements position in the Periodic Table?

A

Its atomic (proton) number - its chemical properties (electronic arrangement).

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9
Q

What determines an elements reactivity?

A

The number of electrons in the outermost shell (group number) - electronic structure.

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10
Q

What happens to metals when they react ionically?

A

Lose electrons - form positive ions

Metals found on LHS of table.

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11
Q

What is Group 1 called? What are some basic properties?

A

The Alkali Metals

Properties:

  • Soft - low density
  • Silvery and shiny surface (until react with oxygen).
  • React with oxygen very well (become dull) - need to be stored in oil to stop oxidation.
  • Relatively low melting points and boiling points compared to other metals.
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12
Q

Why are the alkali metals the most reactive metals?

A

Only have 1 outer electron.

Therefore it only needs to lose that 1 electron to become electronically stable.

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13
Q

What is the trend for reactivity in Group 1? Why? Does the size of the nuclear charge overpower the far distance and greater shielding effect?

A

Reactivity increases from top to bottom.

Lithium = Least Reactive
Francium = Most Reactive 
  • Larger atoms (more shells each period).
  • Nuclear attraction - the larger the atom, the further away the outermost shell is from the nucleus - outer electron can more easily leave.
  • Inner shells screen/shield outer electrons from the nucleus’ positive charge.

No. The increasingly bigger positive nuclear charge going further down group, is massively outweighed by the greater distance and shielding effect.

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14
Q

What is the trend for melting point and boiling point in Group 1? Why?

A

Melting point and boiling point decrease from top to bottom.

Lithium = High BP/MP
Francium = Low BP/MP

The electrons further up the group (e.g lithium) are closer to the nucleus and need more energy to break down.

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15
Q

How do the G1 elements Lithium (Li), Sodium (Na) and Potassium (K) react with water?

A

Lithium - Fizzes on surface of water.

Sodium - Fizzes violently and becomes a molten ball of sodium with a golden yellow flame.

Potassium - It burns with a lilac colour.

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16
Q

What is Group 7 called? What are some basic properties?

A

The Halogens

Properties:

  • Low melting points and boiling points
  • Poor conductors
  • Exist diatomicly (F2, Cl2 etc…)
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17
Q

Why are the Halogens the most reactive non-metals?

A

Contains 7 electrons in the outer shell.

Therefore only needs to to gain 1 electron to become electronically stable.

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18
Q

What is the trend of reactivity in Group 7? Why? Does the size of the nuclear charge overpower the close distance and reduced shielding effect?

A

Reactivity decreases from top to bottom.

Fluorine = Most Reactive
Astatine = Least Reacitve.
  • The smaller the atom, the stronger the electrostatic acctraction from the nuclued.
  • The less shells, the closer the distance between the outer shell and the nucleus.
  • An electron can more easily join an atom with less shells.
  • The less shells, the more the shielding effect from inner shells is reduced.

The closeness of the outershell to the nucleus, outweighs the smaller positive charge (less protons) as an electron recieves a greater electrostatic attraction.

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19
Q

What is the trend of melting point and boiling point in Group 7? Why?

A

Melting boint and boiling point increase from top to bottom.

Astatine = High BP/MP
Fluorine = Low BP/MP

The atoms become larger with greater number of shells, so more energy is needed to overcome these forces.

20
Q

What are displacement reactions?

A

Reactions where a more reactive element displaces a less reactive element in the same group during a chemical reaction.

E.g A more reactive Group 7 element will displace a less reactive Group 7 element.

21
Q

How do you explain trends in terms of reactivity? What does electrostatic attraction depend on?

A

You explain trends in terms of reactivity by the level of electrostatic attraction between electrons in the outermost shell and the nucleus which has a positive charge.

Electrostatic attraction depends on:

  • the distance between the nucleus and outermost electrons.
  • the number of occupied inner shells - provide a ‘shielding effect’.
  • the size of the positive charge on the nucleus (bigger charge = bigger attraction)
22
Q

What is the name of the group that is positioned between Group 2 and 3, where elements are arranged in a large central block?

A

The transition elements / metals

23
Q

What are the physical properties of transition metals?

A
  • Good conductors of electricity and thermal energy.
  • Hard and Strong.
  • High densities.
  • High melting points (except mercury which is liquid at room temperature).
24
Q

What are transition metals used in due to their physical properties?

A

Engineering

25
Q

What are the chemical properties of the transition metals?

A
  • Low reactivity - less reactive than Group 1 metals.
  • Less vigorous reactions - react very timidly - e.g Iron rusts slowly over time - contrasts vigorous reactions of the alkali metals.
26
Q

What are 4 common compounds of transition metals?

A

*Copper Sulfate - Blue
Nickel Carbonate - Pale Green
Chromium Oxide - Dark Green
Manganese Chloride - Purple

*used in test for water

27
Q

What happens to non-metals when they react ionically?

A

Gain electrons - form negative ions

Non-metals found on RHS of table.

28
Q

Why are the noble gases very unreactive?

A

Because they have a very stable electronic arrangement - full shell.

E.g Neon - 2.8

29
Q

Why must alkali metals be stored in oil?

A

Very reactive - must stop them from reacting with oxygen.