C2 Bonding (Part 1) Flashcards
What is ionic bonding?
Ionic bonding is the electrostatic attraction between positive and negative
ions.
It is a relatively strong attraction.
How are ionic compounds
held together?
● They are held together in a giant lattice.
● It’s a regular structure that extends in all directions in a
substance.
● Electrostatic attraction between positive and negative ions holds
the structure together.
State properties of ionic
substances
● High melting and boiling point (strong electrostatic forces between
oppositely charged ions)
● Do not conduct electricity when solid (ions in fixed positions).
● Conduct when molten or dissolved in water - ions are free to move.
Give 5 examples of positive ions
Positive: Na+ Mg2+ Al3+ Ca2+ Rb+
Give 5 examples of negative ions
Negative: Cl− Br− SO4 2− (sulfate) NO3− (nitrate) OH− (hydroxide)
What is important when working out a formula of
an ionic compound?
Ionic compounds are electrically neutral, i.e. positive and negative charges
balance each other.
How are ionic compounds
formed?
Explain in terms of
MgO case.
Reaction of a metal with a non-metal.
Electron transfer occurs:
- metal gives away its outer shell
electrons to non-metal.
Mg is in Group II, so has 2 available outer shell electrons.
O is in Group VI, so can accept 2 electrons to get a full outer shell
configuration.
Mg becomes Mg2+ and O becomes O2− (oxide).
What is a covalent bond?
Covalent bond is a shared pair of electrons between two atoms.
Describe the structure and
properties of simple molecular
covalent substances
- Do not conduct electricity (no ions)
- Small molecules
- Weak intermolecular forces, therefore:
- Low melting and boiling points
How do intermolecular forces
change as the mass/size of the
molecule increases?
They increase. That causes melting/boiling points to increase as well (more energy needed to overcome these forces).
What are polymers?
Polymers are very large molecules (>100s, 1000s of atoms) with atoms linked by
covalent bond
What are thermosoftening polymers?
Thermosoftening polymers - special type of polymers
They melt/soften when
heated.
There are no bonds between polymer chains.
Strong intermolecular forces ensure that the structure is solid at room temperature.
These forces are overcome with heating - polymer melts.
What are giant covalent
substances? Give examples
- Solids, atoms covalently bonded together in a giant lattice.
- High melting/boiling points – strong covalent bonds.
- Mostly don’t conduct electricity (no delocalised e−)
- Diamond, graphite, silicon dioxide.