C2 Flashcards
What do you get at the negative electrode in electrolysis?
positively charged ions gain electrons. This is reduction, and you say that the ions have been reduced.Metal ions and hydrogen ions are positively charged. Whether you get the metal or hydrogen during electrolysis depends on the position of the metal in the reactivity series: The metal will be produced if it is less reactive than hydrogen
Hydrogen will be produced if the metal is more reactive than hydrogen
What happens if an electric current is passed through a concentrated sodium chloride solution
hydrogen gas forms at the negative electrode and chlorine gas forms at the positive electrode. A solution of sodium hydroxide forms.
You might have expected sodium metal to be deposited at the negative electrode. But sodium is too reactive for this to happen, so hydrogen is given off instead.
How would you purify copper in copper manufacture?
In this case, both electrodes are made from copper. The negative electrode gradually gets coated with pure copper as the positive electrode gradually disappears.
How would you electroplate with silver?
The object to be plated, such as a metal spoon, is connected to the negative terminal of the power supply. A piece of silver is connected to the positive terminal. The electrolyte is silver nitrate solution.
What needs to happen for electrolysis to work?
For electrolysis to work, the ions must be free to move. Ions are free to move when an ionic substance is dissolved in water or when melted.
What is the electrolyte?
A substance which in a solution will conduct an electric current.
How are half-equations balanced?
A half-equation is balanced by adding, or taking away, a number of electrons equal to the total number of charges on the ions in the equation.
How would you electroplate with copper?
The object to be plated, such as a metal pan, is connected to the negative terminal of the power supply. A piece of copper is connected to the positive terminal. The electrolyte is coppersulfate solution.
How do you write a half-equation?
Write the formulae of the reactant and product.
Adjust the number of ions, if needed.
Count the number of charges. Add enough electrons so that both sides have the same total number of charges.
How do you use electrolysis to electroplate objects?
The negative electrode should be the object that is to be electroplated
The positive electrode should be the metal that you want to coat the object with
The electrolyte should be a solution of the coating metal, such as its metal nitrate or sulfate
Why is aluminum so expensive?
largely because of the amount of electricity used up in the extraction process.
What does a half-equation show you?
A half-equation shows you what happens at one of the electrodes during electrolysis
What happens during the electrolysis of sodium chloride solution?
Hydrogen ions H+ (from the water) are discharged at the negative electrode as hydrogen gas, H2
Chloride ions Cl– are discharged at the positive electrode as chlorine gas, Cl2
Sodium ions Na+ and hydroxide ions OH– (from the water) stay behind - they form sodium hydroxide solution, NaOH
What happens during electrolysis?
Positively charged ions move to the negative electrode during electrolysis. They receive electrons and are reduced.
Negatively charged ions move to the positive electrode during electrolysis. They lose electrons and are oxidised.
What are electrons shown as in half-equations?
Electrons are shown as e- in half-equations
What happens during electrolysis in the extraction of aluminum?
Aluminium metal forms at the negative electrode and sinks to the bottom of the tank, where it is tapped off. Oxygen forms at the positive electrodes. This oxygen reacts with the carbon of the positive electrodes, forming carbon dioxide, and they gradually burn away. As a result, the positive electrodes have to be replaced frequently. This adds to the cost of the process.
What is electrolysis?
Electrolysis is the process by which ionic substances are decomposed (broken down) into simpler substances when an electric current is passed through them.
How is aluminum extracted before electrolysis?
The bauxite is purified to yield a white powder - aluminium oxide - from which aluminium can be extracted. The extraction is done by electrolysis. But first the aluminium oxide must be melted so that electricity can pass through it. Aluminium oxide has a very high melting point (over 2000°C) so it would be expensive to melt it. Instead, it is dissolved in moltencryolite - an aluminium compound with a lower melting point than aluminium oxide. The use of cryolite reduces some of the energy costs involved in extracting aluminium.
What are the uses of the three products of the electrolysis of concentrated sodium chloride solution
Hydrogen is used as a fuel and for making ammonia
Chlorine is used to kill bacteria in water, and to make bleach and plastics
Sodium hydroxide is used to make soap and bleach
What do you get at the positive electrode in electrolysis?
At the positive electrode, negatively charged ions lose electrons. This is oxidation, and you say that the ions have been oxidised.
What is the name of aluminum ore?
bauxite.
Are nitrates soluble?
Yes, all of them are.
What are alkalis?
Bases that dissolve in water are called alkalis. Alkaline solutions have a pH of more than 7. The stronger the alkali, the higher the pH number
What ions do acids produce when dissolved in water?
When acids dissolve in water they produce aqueous hydrogen ions, H+(aq). For example, looking at hydrochloric acid:
HCl(aq) → H+(aq) + Cl–(aq)
What are neutral solutions?
Neutral solutions have a pH of 7.
How do alkalis react with universal indicator?
They turn universal indicator paper dark blue or purple if they are strongly alkaline, and blue-green if they are weakly alkaline.
How do alkalis react with litmus paper?
Alkalis turn red litmus paper blue.
Are sulfates soluble?
Most are, except for Lead sulfate, barium sulfate
Are hydroxides soluble?
Most aren’t, except for Sodium hydroxide, potassium hydroxide
How do you make an insoluble salt?
You need to react two soluble salts together in a precipitation reaction. if you want to make an insoluble salt XY, mixing X nitrate with sodium Y will always work. The salt forms a precipitate. The precipitate can be filtered, washed with water on the filter paper, and then dried in an oven.
Are chlorides, bromides and iodides soluble?
Most are, except for Silver chloride, silver bromide, silver iodide, lead chloride, lead bromide, lead iodide
How do you crystallize salt solutions?
If the base dissolves in water, you need to add just enough acid to make a neutral solution. Check a small sample with universal indicator paper. Warm the salt solution to evaporate the water. You get larger crystals if you evaporate the water slowly.If the base does not dissolve in water, you need an extra step. You add the base to the acid until no more will dissolve and you have some base left over (called an excess). You filter the mixture to remove the excess base, then evaporate the water in the filtrate to leave the salt behind.
What are the four state symbols?
(s) means solid
(l) means liquid (not the same as dissolved in water - see below)
(g) means gas
(aq) means aqueous (dissolved in water)
How do acids react with universal indicator?
They turn universal indicator paper red if they are strongly acidic, and orange or yellow if they are weakly acidic.
Are carbonates soluble?
Most aren’t, except for Sodium carbonate, potassium carbonate
What are acids?
Substances with a pH of less than 7 are acids. The more strongly acidic the solution, the lower its pH number.
How can we predict the name of the salt formed?
The first part of the name is ‘ammonium’ if the base used is ammonia. Otherwise, it is the name of the metal in the base. The second part of the name comes from the acid used:
Chloride (if hydrochloric acid is used) Nitrate (if nitric acid is used) Sulfate (if sulfuric acid is used)
How can hydrogen be detected?
The hydrogen causes bubbling during the reaction, and can be detected using a lighted splint.
How do acids react with litmus paper?
Acidic solutions turn blue litmus paper red.
What ions do alkalis produce when dissolved in water?
When alkalis dissolve in water they produce aqueous hydroxide ions, OH–(aq). For example, looking at sodium hydroxide:
NaOH(aq) → Na+(aq) + OH–(aq)
What are the equations for when acids react with bases?
acid + metal oxide → salt + water
acid + metal hydroxide → salt + water
What is the neutralization equation?
H+(aq) + OH–(aq) → H2O(l)
What is the equation for when an acid reacts with a metal?
acid + metal → salt + hydrogen
What are bases?
Substances that can react with acids and neutralise them to make a salt and water are called bases. They are usually metal oxides or metal hydroxides.
What are the uses of precipitation reactions?
Precipitation reactions can be used to remove unwanted ions in solution. This is useful for treating drinking water and waste water.
How do neutral solutions react with litmus paper?
They do not change the colour of litmus paper
What is the equation of ammonia in a solution?
NH3(aq) + H2O(l) → NH4+(aq) + OH–(aq) (small numbers)
How do neutral solutions react with universal indicator?
they turn universal indicator paper green
Describe the reaction between anhydrous copper sulfate and water
Water is driven off from hydrated copper sulfate when it is heated, so the forward reaction is endothermic - energy must be transferred from the surroundings for it to happen. The backward reaction is exothermic - energy is transferred to the surroundings when it happens. This is easily observed. When water is added to anhydrous copper sulfate, enough heat is released to make the water bubble and boil.
What are some examples of endothermic reactions?
Electrolysis
The reaction between ethanoic acid and sodium carbonate
The thermal decomposition of calcium carbonate in a blast furnace
What are endothermic reactions?
These are reactions that take in energy from the surroundings. The energy is usually transferred as heat energy, causing the reaction mixture and its surroundings to get colder.
What are some examples of exothermic reactions?
Combustion (burning)
Many oxidation reactions, for example rusting
Neutralisation reactions between acids and alkalis
What do exothermic reactions do?
Exothermic reactions transfer energy to the surroundings. The energy is usually transferred as heat energy, causing the reaction mixture and its surroundings to become hotter.
What are some uses of exothermic reactions?
Exothermic reactions can be used for everyday purposes. For example, hand warmers and self-heating cans for drinks (such as coffee) use exothermic reactions.
If something decomposes, what is the reaction that happens?
endothermic - energy must be transferred from the surroundings for it to happen.
What are some uses of endothermic reactions?
Endothermic reactions can be used for everyday purposes. For example, certain sports injury cold packs use endothermic reactions.
Describe the decomposition of ammonium chloride
Ammonium chloride decomposes when it is heated, so the forward reaction is endothermic - energy must be transferred from the surroundings for it to happen. The backward reaction is exothermic - energy is transferred to the surroundings when it happens.
How are substances measured when calculating the rate of reaction?
The mass of a substance - solid, liquid or gas - is measured with a balance
The volume of a gas is usually measured with a gas syringe, or sometimes an upside down measuring cylinder or burette
Why does using a catalyst increase the rate of reaction?
Catalysts increase the rate of reaction without being used up. They do this by lowering the activation energy needed. With a catalyst, more collisions result in a reaction, so the rate of reaction increases. Different reactions need different catalysts.
What is activation energy?
The minimum energy needed for particles to react