Booklet 8 - Purity, Formulations And Chromatography Flashcards

1
Q

What is a pure substance in chemistry?

A

A pure susbatnce is a single element or compound, thats not mixed with any other substance

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2
Q

How can you test for the boiling and melting points of pure substances?

A

Pure substances melt or boil at specific temperatures
- melting and boiling points data can be distinguished pure substances from mixtures by testing the melting and boiling points of a substance and comparing it with the melting and boiling points of a pure substance, which you can find from the data book

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3
Q

How do you know if a sample is pure?

A

The closer the measured value if the substance is to the actual melting or boiling points the purer the sample is

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4
Q

What two things can impurities in a sample do?

A

1) . Lower the melting point and increase the melting range of the substance
2) . May also increase the boiling point and may result in the sample boiling at a range of temperatures

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5
Q

What is a pure substance in a everyday language?

A

It can mean a substance that has had nothing added to it, so it is unadulterated and in its natural state eg pure milk

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6
Q

What is a formulation?

A

A mixture that has been designed as a useful product

- many products are complex mixtures in which each chemical has a particular purpose

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7
Q

How are formulations made?

A

They’re made by mixing the components in carefully measured quantities to ensure that the product has the required properties

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8
Q

What are some of the examples of formulations?

A

Fuels, cleaning agents, paints, medicines, alloys, fertilisers and foods

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9
Q

What is chromatography?

A

Can be used to separate mixtures and can give information to help identify substances

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10
Q

What’s the mobile phase?

A

Where the molecules can move, always a liquid or a gas

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11
Q

What is the stationary phase?

A

Where the molecules cant move, can be a solid or really thick liquid

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12
Q

What does separation depend on?

A

the distribution of substances between the two phases

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13
Q

What is the process of chromatography?

A

1) . Draw a pencil line on the paper near the bottem using a ruler, pencil is used as ink would run
2) . Spot samples carefully onto the pencil line
3) . Hang in a beaker of solvent, ensuring that the pencil line is above the level of the solvent
4) . Close the lid and allow the solvent to rise up the paper
5) . When near the top, remove the paper and quickly mark with pencil where the solvent reached. This is the solvent front
6) . Allow paper to dry

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14
Q

What does the mobile stage move through?

A

The stationary stage, and anything dissolved in the mobile phase moves with it

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15
Q

What happens to chemicals that spend more time in the mobile phase than the stationary phase?

A

They’ll move futher in the stationary phase

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16
Q

What roles do the stationary and mobile phases play in paper chromatography?

A

The stationary phase is the chromatography paper and the mobile stage is the solvent

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17
Q

Who two things do molecules depend on regarding how much time they spend in a phase in chromatography?

A

1) . How soluble they are in the solvent

2) . How attracted they are to the paper

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18
Q

What happens to molecules with a high solubility in solvent (chromatography)?

A

They are also less attracted to the paper and will spend more time in the mobile phase and they’ll be carried futher up the paper

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19
Q

How can the ratio of the distance moved by a compound to the distance moved by the solvent be expressed?

A

As its Rr value

Rr = distance moved by substance ➗distance moved by solvent

20
Q

What do different compounds have? (Chromatography)

A

They have different Rr values in different solvents, which can be used to help identify the compounds.

21
Q

Why may compounds in a mixture separate into different spots?

A

It depends on the solvent BUT a pure compound will produce a single spot in all solvents

22
Q

What is the test for hydrogen?

A

It uses a burning splint held at the open end of a test tube of the gad, the hydorgen burns rapidly with a pop sound

23
Q

What is the test for oxygen?

A

Uses a glowing splint inserted into a test tube of a gas, the splint relights in oxygen

24
Q

What is the test for carbon dioxide?

A

Uses an aqueous solution of calcium hydroxide (limewater), when CO2 is shaken with or bubbled through limewater, the limewater turns milky (cloudy)

25
Q

What is the test for chlorine?

A

Uses litmus paper, when it is damp it is put into chlorine gas and the litmus paper is bleached and turns white

26
Q

What are flame tests used for?

A

To identify some metal ions (cations), they all produce distinctive colours

27
Q

What colour do lithium ions burn?

A

Crimson red flame

28
Q

What colour do sodium ions burn?

A

A yellow flame

29
Q

What colour do potassium ions burn?

A

A lilac flame

30
Q

What colour do calcium ions burn?

A

A orange-red flame

31
Q

What colour do copper ions burn?

A

A green flame

32
Q

What is a drawback of the flame test technique?

A

If a sample contains a mixture of ions some of the flame colurs can be masked and therfore may not be noted

33
Q

What solution can be added to indentify metal ions (cations)?

A

Sodium hydroxide solution

34
Q

What colour precipitates do solutions of aluminium, calcium and magnesium ions form?

A

White precipitate when sodium hydroxide solution is added

35
Q

What precipitate dissolves in excess sodium hydroxide solution?

A

Aluminium hydroxide precipitate

36
Q

What ions form coloured precipitates when sodium hydroxide solution is added to it?

A

Solutions of copper (II), iron (II) and iron (III)

37
Q

What colour precipitates do copper (II), iron (II) and iron (III) form?

A
  • copper (II) forms a blue precipitate
  • iron (II) forms a green precipitate
  • iron (III) forms a brown precipitate
38
Q

How do you test for carbonate ions in solution?

A

By reacting them with dilute acids to form carbon dioxide gas which can be identified with limewater test

39
Q

How do you test for halide ions in solution?

A

Add dilute nitric acid followed by silver nitrate solution

40
Q

What colours chloride, bromide and iodide go in the prescene of dilute nitric acid and silver nitrate solution?

A
  • Chloride gives a white precipitate of silver chloride
  • bromide gives a cream precipitate of silver bromide
  • iodide gives a yellow precipitate of silver iodide
41
Q

How do you test for sulfate ions?

A

Add dilute hydrochloric acid followed by barium chloride solution. If they’re present a white precipitate of barium sulfate will form

42
Q

What are instrumental methods?

A

Elements and compounds can be detected and identified using imstrumental methods which are accurate, sensitive and rapid

43
Q

What are the advantages of standard lab testing and instrumental methods?

A
  • standard laboratory testing
    1) its available in school
  • instrumental methods
    1) very accurate
    2) sensitive and rapid
    3) only small amount of sample needed
44
Q

What is flame emission spectroscopy?

A

An example of instrumental method used to analyse metal ions in solutions

45
Q

How does flame emission spectroscopy work?

A

The sample is put into a foame and the light given out is passed through a spectroscope.
- the output is a line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations

46
Q

What do different ions have different line spectrums?

A

Different ions will emit different wavelengths so each ion produces a different pattern of wavelength therefore different line spectrum

47
Q

What does the intensity of the spectrum indicate?

A

The concentrations of that ion in the solution