Bonding, structure, and the properties of matter Flashcards

1
Q

What happens to the size of intermolecular forces as the size of molecules increase?

A

The size of intermolecular forces increase (hence higher melting and boiling points for larger molecules)

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2
Q

What are the limitations of the following diagrams to represent ionic structures? Dot and Cross Ball and Stick

A

• Dot and cross: Doesn’t show the structure of the ionic compound, the size or arrangement of ions. • Ball and stick: Suggests gap between ions which aren’t in fact there.

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3
Q

Describe the structure and bonding of Graphite.

A

• Giant covalent structure • Each carbon forms three covalent bonds with other carbon atoms • Forms layers of hexagonal rings • No covalent bonds between layers • One electron from each carbon atom is delocalised

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4
Q

What state are most polymers at room temperature? Why?

A

• Solid • Because they are large molecules, with strong intermolecular forces, hence relatively high melting and boiling points (compared with small molecules).

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5
Q

Diamond and graphite are made out of a single element. Name this element.

A

Carbon

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6
Q

Why do small molecules usually have relatively low melting and boiling points?

A

• They have weak forces between molecules (intermolecular forces) • It is the intermolecular forces that are overcome, not the covalent bonds, when the substance boils.

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7
Q

Describe how sodium and chlorine bond to form sodium chloride.

A

• The sodium atom loses one electron to become a sodium ion • The chlorine atom gains one electron to become a chloride ion • The positive sodium ion is attracted to the negative chloride ion to form sodium chloride.

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8
Q

What charge do the ions of elements in the following groups have?: a) Group 1 b) Group 2 c) Group 6 d) Group 7

A

a) Group 1: + b) Group 2: 2+ c) Group 6: 2- d) Group 7: -

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9
Q

What are cylindrical fullerenes called and why are they useful?

A

• Nanotubes • They have a high length to diameter ratio making them useful for nanotechnology, electronics and materials.

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10
Q

Do metals have high or low melting points and boiling points?

A

High melting and boiling points

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11
Q

Describe the properties of Diamond.

A

• Hard • Very high melting point • Doesn’t conduct electricity

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12
Q

Describe the structure and bonding of Diamond.

A

• Giant Covalent Structure • Each carbon forms four covalent bonds with other carbon atoms

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13
Q

What type of bond exists between metals and non-metals in a compound?

A

Ionic Bond

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14
Q

What element are all fullerenes made from?

A

Carbon

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15
Q

What is graphene?

A

A single layer of graphite

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16
Q

Why are metals good conductors of heat and electricity?

A

They have delocalised electrons that can carry the charge (in terms of conducting electricity) or transfer energy (in terms of conducting heat)

17
Q

What type of bond exists in non-metal elements and compounds?

A

Covalent Bond

18
Q

In which type of bond are electrons transferred?

A

Ionic bond

19
Q

What bonds must be overcome in order to melt or boil giant covalent structures?

A

The strong covalent bonds between the atoms.

20
Q

Describe the structure and bonding in a metal.

A

• Metallic bonding • Strong metallic bonds • Giant structure of metal atoms in regular pattern • Outer shell electrons are delocalised

21
Q

When atoms gain or lose electrons to become ions, they will have the electron structure of what group of elements?

A

Noble gases

22
Q

What is the name for the forces that exist between ions in an ionic bond?

A

Electrostatic forces

23
Q

In which type of bond are electrons shared?

A

Covalent bond

24
Q

What type of bonding exists in metallic elements and alloys?

A

Metallic bonding

25
What do the following state symbols represent? a) s b) l c) g d) aq
a) Solid b) Liquid c) Gas d) Aqueous (dissolved in water)
26
What type of bonds exist in large molecules, such as polymers?
Covalent bonds
27
What is the chemical formula of Buckminsterfullerene?
C60
28
What charge do non-metal ions have?
Non-metal ions are negative
29
Can molecules conduct electricity? Give a reason for your answer.
No, because they have no overall electric charge.
30
Describe the structure of fullerenes
Mostly hexagonal rings of carbon (will also have rings with 5 or 7 carbon atoms). Can be spherical or cylindrical in shape.
31
What is the relationship between the forces between particles and a substance’s melting and boiling points?
The stronger the forces between particles, the higher the melting and boiling points (or vice versa)
32
Give three examples of giant covalent structures.
• Diamond • Graphite • Silicon dioxide
33
Name two uses of graphene.
Used in electronics and composites
34
Why do ionic compounds have high melting and boiling points?
Because a lot of energy is needed to break the many strong bonds.
35
Why do molten or aqueous solutions of ionic compounds conduct electricity?
Ions are free to move so charge can flow
36
What charge do metal ions have?
Metal ions are positive
37
Small molecules contain what type of bonds?
Covalent bonds
38
Describe the structure and bonding of an ionic compound.
• Ionic bonding • Giant structure of ions • Lattice structure • Oppositely charged ions held together by electrostatic forces acting in all directions
39
What is the name for the electrons that are free to flow in metallic bonding?
Delocalised electrons