Bonding & Structure Flashcards
Why do atoms bond?
- They aim for greater stability and reduce energy in their structure
- Generally aim for full energy shells
What are the types of bonds?
- They are all an electrostatic force of attraction between oppositely charged species
- The three types are
Ionic: involves gain or loss of electrons to form ions.
Covalent: involves sharing of electoons
Metallic: involves loss of electrons
Tell me about ionic bonds.
- Ionic bonds form through the electrostatic force of attraction between oppositely charged ions
- Atoms become stable by gaining or losing electrons to get full shells
What are cations and anions?
Cations: have a positive charge and have lost electrons
Anions: have a negative charge and have gained electrons
What are the properties of ionic compounds?
- All have an overall charge of 0
- High melting & boiling point: because there are billions of ions attracted so a lot of energy is needed to overcome the ionic bonding
- When solid does not conduct electricity: because the ions are not free to move
- Ionic substances are soluble in water: because water is a polar solvent that disrupts the ion
- Conducts electricity when dissolved in water or molten: because the ions are free to move
Tell me about covalent bonding.
- Mostly between non-metals
- Made through the sharing of electrons
- If atom needs one electron, it must share one of its own
What are the properties of covalent substances?
- Low melting & boiling points: breaking the attractive forces of molecules is easy
- Do not conduct electricity as the atoms are neutral and there are no mobile ions or electrons to pass the charge
- Most do not dissolve in water
How do metallic bonds work?
- In metals, atoms are tightly packed together and form a regular lattice
- Tight packing allows outermost electrons to separate from atoms
- Results in lattice of ions in a sea of electrons
- Ions have regular pattern so metals are crystalline
- Released electrons cause atoms to have a positive charge
- Metallic bonding is the electrostatic force of attraction between positive metal ions with sea of electrons
- Structure of metals greatyly impact density, conductivity, malleability, and melting and boiling points
What causes metals to be malleable?
They have layers so if a metal atom gets moved, it moves to the next layer
What is an alloy?
Metals made by combining 2 or more metals.
Define simple covalents and giant molecular structures.
- Simple covalents have a formula
- Giant molecular structures: sometimes millions of atoms joined together produce a giant lattice and don’t have a chemical formula
Tell me about graphite
- Giant covalent
- 3 covalent bonds per carbon atom
- High melting and boiling point due to strong covalent bonds
- Conductor due to delocalised electrons
- Soft and brittle
Tell me about diamond
- Giant covalent
- 4 covalent bonds per c atom
- High melting and boiling point due to strong covalent bonds
- Insulator due to no delocalised electrons
- Very hard and strong
Tell me about graphene
- Giant covalent
- 3 covalent bonds per carbon atom
- Very high melting and boiling point due to strong covalent bonds
- Conductor due to delocalised electrons
- Very strong
Tell me about buckminsterfullerene
- Simple molecular
- C 60
- Strong covalent bonds
- 3 covalent bonds per carbon atom
- Low melting and boiling point due to weak intermolecular forces
- Insulator because electron movement is inhibited
- Soft and brittle