Bonding and Orbitals Flashcards

1
Q

What do atomic orbitals form when they combine?

A

Molecular orbitals

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2
Q

When is a bonding orbital formed?

A

When the signs of the wave functions of the atomic orbitals are the same

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3
Q

When is an antibonding orbital formed?

A

When the signs of the wave functions of the atomic orbitals are different

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4
Q

Which orbitals are more stable: bonding or antibonding orbitals?

A

Bonding orbitals

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5
Q

What are the s and p characters of an sp3 orbital?

A

25% s and 75% p

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6
Q

What are the s and p characters of an sp2 orbital?

A

33% s and 67% p

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7
Q

What type of bonds do sp3 orbitals form?

A

Single

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8
Q

What type of bonds do sp2 orbitals form?

A

Double

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9
Q

What type of bonds do sp orbitals form?

A

Triple

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10
Q

What are the s and p characters of an sp orbital?

A

50% s and 50% p

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11
Q

How do the orbitals of resonance structures differ?

A

Differ in their placement of electrons in hybridized p orbitals

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12
Q

What is the true electron density when a molecule has different resonance structures?

A

A weighted average of the resonance structures

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13
Q

What geometry do sp3 orbitals form?

A

Tetrahedral with 109.5 bond angles

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14
Q

What geometry do sp2 orbitals form?

A

Trigonal planar with 120 bond angles

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15
Q

What geometry do sp orbitals form?

A

Linear with 180 bond angles

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16
Q

What kind of orbitals are pi bonds made of?

A

2 p orbitals

17
Q

What kind of orbitals are sigma bonds made of?

A
  • s and s orbitals
  • p and p orbitals
  • s and p orbitals
  • hybridized orbitals
18
Q

How does orbital overlap affect bond strength?

A

The greater the overlap, the greater the bond strength

19
Q

What is a sigma bond? What do they enable?

A

Head on overlap of orbitals

Enable free rotation around the bond

20
Q

What types of bond in a double bond?

A

1 sigma and 1 pi

21
Q

What is a pi bond? What does it restrict?

A

Side by side overlap of orbitals

Restricts free rotation

22
Q

What does increased s character imply?

A

Increased stability because decreased energy