Bonding Flashcards
Molecular orbitals are formed with
The combination of 2 atomic orbitals
Lower-energy bonding orbitals are produced when the signs are the
Same
Higher-energy ANTIbonding orbitals are produced when the signs are
Different
Sigma bonds are when molecular orbitals are formed with
Head-to-head overlap
Sigma bonds are
Single bonds
Which sigma bonds are stronger?
The shorter ones
π bonds consist of
2p orbitals overlapping in parallel fashion
π bonds can’t exist independently of a
Sigma bond
π bonds are weaker than
Sigma bonds
Which bonds need to be broken first?
π bonds
Double bonds consist of
1 sigma + 1 π bond
Triple bonds consist of
1 sigma + 2 π bond
Single bonds contain:
- Sigma bond
- sp3 hybridization
- 109.5º
Double bonds contain
- Sigma + 1 π bond
- sp2 hybridization
- 120º
Triple bonds contain
- Sigma + 2 π bond
- sp hybridization
- 180º