bonding Flashcards

1
Q

ionic bonding

A

electrostatic attraction between anions and cations

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2
Q

ionic compounds

A

electrostatic forces not localised - attract in all directions to form giant ionic lattices

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3
Q

ionic compound melting/boiling points

A

high temperatures provide lots of energy
need to overcome strong electrostatic attraction between ions
higher charge density, higher bp

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4
Q

ionic compounds solubility

A

dissolve in polar solvents
polar molecules break down lattice and surround ions
high Q density: more energy to overcome ionic
more energy released
(ion-dipole)

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5
Q

charge density

A

higher charge on the atom, higher charge density
smaller size, higher charge density
very electro(negative/positive)

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6
Q

Soluble Salts

A

All ammonium, Group 1 and nitrate salts
All halide salts (except silver and lead)
All sulfate salts (except calcium, barium, silver and lead)

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7
Q

Insoluble salts

A

All carbonate / Hydroxide salts (except Group 1 and ammonium)
All silver and lead salts (except nitrates)

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8
Q

Covalent Bonds

A

Strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms
overlap of orbitals = localised

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9
Q

no. of covalent bonds
“octet expansion”

A

depends on the shell number
n=2 means a max of 8 electrons
n=3 means max 18 electrons (fill 3d)

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10
Q

dative covalent bonds

A

lone pair on an atom fills orbital in other bonding atom

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11
Q

ionic vs covalent

A

0.0<ΔEN<0.5 - covalent
0.5<ΔEN<1.8 - polar covalent
ΔEN>1.8 - ionic

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