bonding Flashcards
ionic bonding
electrostatic attraction between anions and cations
ionic compounds
electrostatic forces not localised - attract in all directions to form giant ionic lattices
ionic compound melting/boiling points
high temperatures provide lots of energy
need to overcome strong electrostatic attraction between ions
higher charge density, higher bp
ionic compounds solubility
dissolve in polar solvents
polar molecules break down lattice and surround ions
high Q density: more energy to overcome ionic
more energy released
(ion-dipole)
charge density
higher charge on the atom, higher charge density
smaller size, higher charge density
very electro(negative/positive)
Soluble Salts
All ammonium, Group 1 and nitrate salts
All halide salts (except silver and lead)
All sulfate salts (except calcium, barium, silver and lead)
Insoluble salts
All carbonate / Hydroxide salts (except Group 1 and ammonium)
All silver and lead salts (except nitrates)
Covalent Bonds
Strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms
overlap of orbitals = localised
no. of covalent bonds
“octet expansion”
depends on the shell number
n=2 means a max of 8 electrons
n=3 means max 18 electrons (fill 3d)
dative covalent bonds
lone pair on an atom fills orbital in other bonding atom
ionic vs covalent
0.0<ΔEN<0.5 - covalent
0.5<ΔEN<1.8 - polar covalent
ΔEN>1.8 - ionic