Basic organic. Flashcards

1
Q

Saturated definition.

A

Single bonds only.

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2
Q

Unsaturated definition.

A

Have C=C double bonds(multiple).

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3
Q

Homologous series meaning.

A

Family of compounds w/ similar chemical properties whose successive members differ by the addition of a -CH2 group.

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4
Q

Functional group meaning.

A

A group of atoms largely responsible for a molecule’s chemical properties/characteristic reactions.

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5
Q

Aliphatic hydrocarbons.

A

C atoms joined to each other in straight or branched chains or non-aromatic rings.
Alkenes(at least 1 C=C)
Alkanes(single C-C)
Alkynes(at least 1 triple carbon carbon bond)

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6
Q

Alicyclic hydrocarbons.

A

C atoms are joined to each other in ring structures w/ or w/o branches.

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7
Q

Aromatic hydrocarbons.

A

Some or all of the C atoms are found in a benzene ring.

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8
Q

Carbon number and stem name.

A

1=meth
2=eth
3=prop
4=but
5=pent
6=hex
7=hept
8=oct
9=non
10=dec.

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9
Q

Naming organic compounds.

A

Practice questions.

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10
Q

Functional groups.

A

Aldehyde-CHO
Ketone C=O
Ester -COOC
Acyl chloride -COCl
Amine -NH2
Nitrile -CN

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11
Q

General formulas.

A

Alkanes= CnH2n+2
Alkenes=CnH2n
Alcohols=CnH2n+1OH
Carboxylic acids= CnH2nO2
Ketones= CnH2nO

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12
Q

Displayed, structural formulas.

A

Practice questions.

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13
Q

Skeletal formulas.

A

A line= a single bond
Intersection between 2 lines= a carbon atom
End of a line= a -CH3 group
Still write functional groups
Double bond C=C= a double parallel line
Remove:
-all C and H labels from carbon chains
-any bonds to H atoms.
PRACTICE QUESTIONS.

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14
Q

Alkyl group.

A

CnH2n+1
Made by removing a H atom from an alkane.

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15
Q

Which end to count from?

A

Start counting carbons from the end with the highest total mass
The biggest Mr is the starting point for Carbon number 1.
PRACTICE.

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16
Q

Structural isomers.

A

Compounds w/ the same molecular formula but different structural formulae.
PRACTICE drawing diff isomers.

17
Q

Homolytic fission.

A

One way a covalent bond breaks.
Each bonded atom takes one of the shared pair of electrons from the bond.
Each atom has a single unpaired electron.
A radical.
PRACTICE DRAWING OUT MECHANISM.

18
Q

Radical definition.

A

An atom or groups of atoms w/ an unpaired electron.

19
Q

Heterolytic fission.

A

When covalent bond breaks by this:
one of the bonded atom takes both of the electrons from the bond
Atom w/ both electrons=negative ion
Atom that takes none=positive ion.
PRACTICE DRAWING OUT.

20
Q

Curly arrows.

A

Used to show the movement of electron pairs when bonds are being broken or made.

21
Q

Reactions mechanisms.

A

PRACTICE QUESTIONS.

22
Q

Addition reactions.

A

2 reactants–> 1 product.

23
Q

Substitution reactions.

A

An atom or a group of atoms is replaced by a different atom or group of atoms.

24
Q

Elimination reactions.

A

The removal of a small molecule from a larger one.
One reactant molecule form 2 products.