balsams And Latex Flashcards
sn: Tolu balsam
Myroxylon balsamum
family: tolu balsam
fabaceae
color: tolu balsam with ferric chloride
green
odor: tolu balsam
benzaldehyde
cons (5): tolu balsam
toluresinotannol (free cinnamic acid, free benzoic acid, benzyl cinnamate, benzyl benzoate
uses (4): tolu balsam
- compound benzoin tincture
- expectorant
- flavorant in chewing gum
- perfumery
sn: peruvian balsam
Myroxylon pereirae
fam: peruvian balsam
Fabaceae
prod. of balsam: peruvian balsam
boiling bark in water
cons (3): peruvian balsam
benzoyl citrate, benzoyl benzoate, cinnamyl cinnamate
uses (5): peruvian balsam
- protectant, rubefacient, parasiticide, antiseptic, vulnerary
- antiseptic dressing
only balsam not part of compound benzoin tincture
peruvian balsam
sn: Siam benzoin/ Asa dulcis
Styrax benzoin
fam: Siam benzoin/ Asa dulcis
Styracaceae
how is Siam benzoin/ Asa dulcis produced?
by incisions - first secretion is very sticky (rejected); succeeding cuts yield harder secretions
which is more expensive? Sumatra benzoin or Siam benzoin/ Asa dulcis
Siam benzoin/ Asa dulcis
odor: Siam benzoin/ Asa dulcis
vanilla-like odor
uses internally (2): Siam benzoin/ Asa dulcis
expectorant, antiseptic
cons (2): Siam benzoin/ Asa dulcis
coniferyl benzoate (major), siaresinol
uses (4): Siam benzoin/ Asa dulcis
food, drinks, perfumery, and toiletry
ingredient for Friar’s balsam
Siam benzoin/ Asa dulcis (Styrax benzoin)
sn: sumatra benzoin
Styrax tonkinensis
fam: sumatra benzoin
styracaceae
cons (1): sumatra benzoin
20% free balsamic acids (Cinnamic and benzoic; 2:1 ratio)
uses (5): sumatra benzoin
- source of benzoic acid (commonly used as preservative in Whitfield’s ointment for athlete’s foot)
antiseptic, stimulant, expectorant, diuretic
differentiating Siamese from Sumatra benzoin: warming with KMnO4
Sumatra: faint odor of benzaldehyde
differentiating Siamese from Sumatra benzoin: ferric chloride
green color to Siamese benzoin
SN (2) and common names (2): storax
- Liquidambar orientalis (Levant storax/ Oriental sweetgum)
- L. styraciflua (American storax/ sweetgum)
fam: storax
Hammamelidaceae
cons (2): storax
- cinnamic acids
- storesins (alpha- amorphous but crystalline with potassium; beta - white flasks that do not crystallize with potassium)
uses (5): storax
cigarette flavorant, stimulant, expectorant, antiseptic
Compound benzoin tincture components
Storax, Tolu Balsam, Aloe, Benzoin (STAB)
use of compound benzoin tincture
topical protectant
benzoic acid preparation before
sublimation of sumatra benzoin
benzoic acid preparation now
synthetic
uses (4): benzoic acid
antifungal, preservative of food, pharmaceutical preparations, Whitfield’s ointment
whitfield’s ointment uses (2)
athlete’s foot and ringworm
components of whitfield’s ointment (2)
salicylic acid + benzoic acid
source (common and sn): rubber/ caoutchouc
rubber tree (Hevea brasiliensis)
fam: Rubber tree (Hevea brasiliensis)
Euphorbiaceae
how is rubber obtained
injuring the bark
alternative for natural sources in production of rubber/ caoutchouc
Parthenium argentatum
what is done? following the initial cleaning of the latex in vats
it is coagulated and bleached by tx w/ formic acid and bleaching agent
how do latex emerge?
as blocks and passed through a mill 30x –> thin layers ready for further processing
what are present in the latex of Papaveraceae
alkaloids
proteolytic enzyme found in the latex of Carica
papain
what is cultivated in Malaysia for commercial use?
Hevea brasiliensis (Euphorbiaceae)
can rubber (Ficus) be vulcanized?
yes
Source: gutta percha
Palaquium gutta
Family: gutta percha (Palaquium gutta)
Sapotaceae
Can gutta percha be vulcanized?
No
Temp where gutta percha becomes plastic when heated
45-60*C
Gutta percha when heated at 45-60*C becomes?
Plastic
T or F: Gutta percha should be preserved under water in well-closed
containers protected from light
T
Uses (4): gutta percha
- Used in the form of chloroformic solution as means of applying drugs to
the skin - gutta-percha tissue for covering moist dressings and in manuf of surgical instruments
- Dentistry
- Root canal tx
a polyisoprenoid consisting of a mixture of cis and trans –C5 isoprenoids obtained from Manilkara zapota (Sapotaceae), the sapodilla plum
Chicle
Source: chicle
Manilkara zapota (Sapotaceae)
Use: chicle
Base used for original chewing gum
Source: balata
dried latex obtained from Mimusops balata (Sapotaceae)
possesses the general properties of chicle & is employed in the manufacture of bubble gum
Balata
Use: balata
Manuf of bubble gum
Sn: Indian rubber
Ficus elastica
Fam: indian rubber (Ficus elastica)
Moraceae
Cons (1): indian rubber
Caotchouc
Use (1) indian rubber (Ficus elastica)
Potential for worm and dermatitis
Sn: chico/ sapodilla
Achras zapota/ Manilkara zapota
Fam: chico/ sapodilla (Achras zapota/ Manilkara zapota)
Sapotaceae
Cons (1): chico/ sapodilla
Mixture of C5 isoprenoids
Use: CHICO/ SAPODILLA (Achras zapota/ Manilkara zapota)
Base used for original chewing gum