B1.1-carbohydrates and lipids Flashcards

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1
Q

variety of carbon structure

A

carbon makes 4 bonds
-can be 4 single or a mixture of single and double to either carbon atoms of non-metallic elements
-can form diverse carbon patterns
-can form branched, unbranched, sing-ring, multiple-ring chains

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2
Q

elements and how many covalent bonds they can make

A

hydrogen-1
oxygen-2
nitrogen-3
carbon-4
phosphorus-5

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3
Q

common functional groups

A

-OH-hydroxyl
-NH2-amine
-COOH-carboxyl
-H2PO4-phosphate

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4
Q

general common categories of molecules
molecule-subcategory-exmples

A

carbohydrates; monosaccharide (glucose, fructose, ribose), disaccharide(maltose, lactose, sucrose), polysaccharide(starch, glycogen).

proteins- enzymes, antibodies, peptide hormones

lipids; triglycerides(fat stored in adipose tissue), phospholipids(bilayers), steroids (some hormones)

-nucleic acid; nucleotides (DNA, RNA, ATP)

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5
Q

macromolecules

A

large molecules made from monomers; lipids, proteins, carb, aminoacids

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6
Q

hydrolysis

A

reaction that breaks down covalent bonds between monomers in which a water molecule is ‘split’ into H and OH and attach too two different molecules

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7
Q

condensation reaction

A

two molecules joining together to form a larger molecule and releases one water molecule

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8
Q

why condensation reactions are important

A

to break down polymers into monomers which can be absorbed into the bloodstream which enters the cell to build into macromolecule again or as a store of energy

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9
Q

classification of carbohydrates

A

monosaccharide- 1 sugar molecule (glucose, ribose, fructose)

disaccharide-2 sugar molecules (sucrose, maltose, lactose)

polysaccharide-many sugar molecules (starch, glycogen, cellulose)

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10
Q

types of monosaccharides

A

1) pentose monosaccharide: ribose/ deoxyribose -composed of 5 carbons

2) hexose monosaccharide: glucose- 6 carbons

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11
Q

properties and uses of glucose

A

-polar molecule so it is soluble in water
-transported in body fluids
-molecular stability- strong covalent bonds
-high energy yield- good primary energy store.

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12
Q

what is a polysaccharide

A

-long chain of glucose molecules
-combined by condensation reactions
-starch in plants, glycogen in animals
-starch and glycogen are compact due to coiling and branching

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13
Q

coiling structure of polysaccharide
- amylose and amylopectin structure

A

-to make as compact as possible, there are different bonds between glucose molecules;
-alpha 1-4 linkage
-alpha 1-6 linkage

amylose: carbon 1 bonded to carbon 4 of adjacent, forming linear helix shape

amylopectin: carbon 1-6 bonds which forms branches

!!both polymers of starch

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14
Q

structure of glycogen

A

polysaccharide made from glucose monomers bonded similarly to amylopectin but with more numerous branches

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15
Q

overview of types of polysaccharides

A

1) starch- composed of two polysaccharide molecules;
-amylose=long chain of alpha glucose
-amylopectin=long chain of alpha glucose with branches
2)glycogen-short term energy in animals, many branches of alpha glucose
3) cellulose-unbranched polysaccharides made from beta glucose with every second flipped

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16
Q

structure of cellulose

A

1-4 linkage between beta glucose molecules, every second beta molecule flipped resulting in straight chain
-linear polymer forms fibers which join together with hydrogen bonds to form microfibrils, allowing strength of cell wall

17
Q

what is a glycoprotein

A

(carbohydrate and protein)
-integral protein located within phospholipid bilayer of cells
-has a chain of carbohydrates attaches, which is a specific shape and can act as an antigen

18
Q

roles of glycoproteins

A

-cell to cell adhesion, forming tissues
-receptors for hormones-when hormones bind to specific glycoprotein receptors, changes metabolism
-cell to cell chemical communication
-recognitions of body self cells versus non self body cells for immune response

19
Q

glycoproteins in ABO blood types

A

-the glycoprotein on surface of red blood cell determines persons blood type
-acts as an antigen- if glycoprotein is not recognized as self by immune system
-red blood cells can have antigen A or B/ both/neither and the immune system does not produce antibodies against antigens that are present in blood
-O type has neither A or B proteins

20
Q

what are antigens

A

substance which stimulates an immune response and production of antibodies

21
Q

what happens if someone gets donated wrong blood type

A

-agglutination=red blood cells clump together
-haemolysis= destruction of RBC which causes blood clotting

22
Q

properties of lipids

A

-lipids include- fats, oils, waxes, steriods
-can dissolve in non-polar substances
-hydrophobic, don’t dissolve in water

23
Q

structure of triglyceride

A

-contains one glycerol molecule and 3 fatty acids
-formed by condensation reaction

-1 glycerol + 3 fatty acids= 1 triglyceride + 3 water molecules

24
Q

structure of phospholipid

A

contains one glycerol molecule, 1 organic phosphate group and 2 fatty acids
-formed by condensation reaction

1 glycerol + 2 fatty acids + 1 organic phosphate = 1 phospholipid + 3 water molecules

25
Q

what a fatty acid is composed of

A

-terminal carboxyl group
-hydrocarbon chain
-methyl group

26
Q

what fats/oils are

A

fats= triglycerides solid at room temp
oils=triglycerides liquid at room temp

27
Q

properties of fatty acids

A

1) saturated fatty acid= contains single bonds between carbon in hydrocarbon chain
(has high melting point, ‘fats’ solid at room temp, stores excess energy in animals)

2)monounsaturated fatty acid= fatty acids with one double bond in hydrocarbon chain
(has lower melting point, ‘oils’ liquid at room temp, many plants use as long term energy store)

3) polyunsaturated fatty acids= fatty acids with more than one double bond in hydrocarbon chain
‘’’’

28
Q

two different bonds in fatty acid

A

cis= hydrogens are on the same side of the chain, resulting in curved shape
trans=hydrogens on opposite side of chain, resulting in straight chain

29
Q

examples of saturated and unsaturated fats

A

saturated= red meat, butter
mono/poly unsaturated (cis) fats= olive oil, fish oil

30
Q

why triglycerides are suited for adipose tissue

A

-animals store fat in adipose tissue under the skin, fat stored in form of triglycerides
-lipids store more then twice the energy content of carbohydrates
-fats have low thermal conductivity
-act as an insulator and help endotherms

31
Q

formation of phospholipid bilayers as consequences of hydrophobic and phillic regions

A

-phospholipids are amphipathic meaning they have both hydrophilic (head) and hydrophobic (tail) regions
-this will form a bilayer in water as the hydrophilic heads will attract water and the tails will remain on the inside

32
Q

steroid hormones shape and properties

A

-lipids with 4 carbon ring and hydrocarbon chain shape
properties;
-hydrophobic
-able to diffuse directly through phospholipid bilayer and dissolve in the hydrophobic fatty acid tail on inside of bilayer because of its non-polar and hydrophobic properties
-examples are oestradoil and testosterone