Atoms And Reactions Flashcards

1
Q

What is the relative atomic mass?

A

Weighted mean mass of an atom of an element compared to 1/12 of an atom of carbon 12

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2
Q

What is the relative isotopic mass?

A

Mass of an atom of an isotope compared with 1/12 of and atom of carbon 12

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3
Q

What is the relative molecular mass or relative formula mass?

A

The average mass of a molecule or formula unit compared to 1/12th of the mass of an atom of carbon 12

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4
Q

What is the relative mass of protons, neutrons and electrons?

A

Proton and neutron - 1

Electron - 1/2000

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5
Q

What is Avogadro’s constant?

A

6.02 x 10(23)

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6
Q

What are the units for Molar Mass?

A

grams per mol - g mol-1

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7
Q

What is the empirical formula ?

A

the smallest whole number ratio of atoms of each element in a compund

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8
Q

What is the molecular formula?

A

the actual number of atoms of each type of element in a molecule

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9
Q

What is an ionic equation?

A

only shows reacting particles

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10
Q

What are the formulas of the molecular ions nitrate, carbonate, sulphate, hydroxide, ammonium, zinc ion and silver ion?

A
nitrate - NO3(-)
carbonate - CO3(-2)
sulphate - SO4(-2)
hydroxide - OH-
ammonium - NH4(+)
zinc ion - Zn(2+)
silver ion - Ag+
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11
Q

Ionic compounds are made when …………..

A

positive and negative ions bond together

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12
Q

salts are ………………

A

ionic compounds - lattice of positive and negative ions

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13
Q

What is water of crystallisation?

A

hydrated if contains water of crystallisation - water in lattice
anhydrous if not

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14
Q

acids are ……

A

proton donors

when mixed with water release H+ - produce H+ ions in an aqueous solution

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15
Q

bases are ………..

A

proton acceptors

alkalis (soluble bases) produce OH- ions in an aqueous solution

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16
Q

reactions between acid and water and bases and water are ……………..

A

reversible

17
Q

explain reactions with strong and weak bases and acids

A

strong acids - very little reverse, nearly alll the acid will dissociate in water releasing nearly all the h+ ions
strong bases - nearly all the base dissociates in water, lots of OH- ions are produced
weak acids - backward reaction favoured, only small amount dissociates, only few H+ produced
weak bases - ionise only slightly, small amount of bases dissociates, few OH- ions produced

18
Q

in a neutralisation reaction between acid and alkali ………….is produced

A

salt and water

19
Q

what are the four equations for acids with metal and metal compounds?

A

metal + acid = metal salt + hydrogen
metal oxide + acid = salt + water
metal hydroxide + acid = salt + water
metal carbonate + acid = metal salt + carbon dioxide + water

20
Q

what happens when ammonia reacts with acid?

A

ammonia + acid = ammonium salt

21
Q

how do you carry out a titration?

A

measure out some alkali using a pipette and put it in a flask with some indicator
fill a burette with acid
do a rough titration - idea of end point
do an accurate titration - read the bottom of the meniscus
work out the exact amount of acid used to neutralise the acid - final reading - initial reading = titre

22
Q

what colours does methyl orange and phenolphthalein turn in acid and alkali?

A

methyl orange - yellow to red acid to alkali

phenolphthalein - pink to colourless acid to alkali

23
Q

what is an analyte?

A

the solution with an unknown concentration

24
Q

what is a standard solution? how is it made?

A

a solution with a precise known concentration
weigh the require mass of solid
transfer solid to a beaker - use some water to wash any solid bits into the beaker
add water to the beaker to completely dissolve the solid - use a glass rod to stir
transfer the solution to a volumetric flask - rinse the beaker and glass rod transferring the water to the flask
fill the flask to the graduation line with water
put the lid on and turn to mix

25
Q

what is reaction stoichiometry?

A

how many moles of one reactant react with how many moles of another reactant

26
Q

what are polyprotic acids?

A

donate more than one proton

27
Q

What is her theoretical yield?

A

the mass of product which should be made in a reaction if no chemicals are lost in the process

28
Q

What is the percentage yield?

A

the actual amount of product you collect as a percentage of the theoretical yield

29
Q

what is atom economy?

A

a measure of the proportion of reactant atoms that become part of the desired product in the balanced chemical equations
atom economy = molecular mass of desired product/ sum of molecular masses of all products x 100

30
Q

what is an addition reaction?

A

the reactants combine to form a single product

atom econly = 100 no atoms are wasted

31
Q

what is a substitution reaction?

A

some atoms from one reactant are swapped with atoms from another reactant

32
Q

Why do chemical companies chose reactions with a high atom economy??

A

environmental and economic benefits
at low atom economy - lots of waste, cost t separate desired product from waste, less sustainable - raw materials(limited supply) are wasted,
lower temperatures are cheaper and more environmentally friendly
renewable sources are better

33
Q
what is the oxidation number of 
uncombined elements
identical elements
monatomic ion 
oxygen
hydrogen?
A

uncombined elements = 0
identical elements = 0
monatomic ion = same as its charge
oxygen = -2 except in peroxides = -1 or O2 = 0
hydrogen = +1 except in hydroxides = -1 or H2 = 0

34
Q

ions ending in ate contain ……………..

A

oxygen and element

35
Q

What is a redox reaction?

A

reduction and oxidation happen simultaneously

36
Q

what is an oxidising agent?

A

accepts electrons and gets reduced

37
Q

what is an reducing agent?

A

donates electrons gets oxidised

38
Q

Metals are ……..when they react with acids

A

oxidised