Atoms Flashcards

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1
Q

what did Thomson model explain

A

1) uniformly distributed positive charge
2) electron->watermelon seed
3)plum pudding model

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2
Q

limitation of the Thomson model

A

1) origin of spectral series
2)alpha particle scattering

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3
Q

Rutherford model

A

1)small and massive central core of +ve charge
2)the size of nucleus is very small

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4
Q

Rutherford model limitation

A

1)cannot explain the stability of atom
2)they would emit a continuous spectrum instead of the actually observed line spectrum

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5
Q

BOHR’S ATOMIC MODEL

A

1)Electrons revolve around the nucleus in fixed circular paths called
Orbits or Shells.
2)Electron in its own shell does not lose or gain energy. It loses or
gains energy when it jumps from one shell to another
3)The Angular Momentum of electron is quantized in the shell.
L = (nh)/(2pi)

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6
Q

Bohr radius of hydrogen

A

r = 0.53 (n^2)/z A

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7
Q

bohr radius formula

A

(Eon^2h^2)/pimz*e^2

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8
Q

velocity of electron

A

v = 2.186 x 10^6 * z/n

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9
Q

potential energy of electron

A

P.E=-e^2/(4piEo*r)

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10
Q

energy of hydrogen in the Nth orbit

A

E=-13.6/n^2 eV

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11
Q

energy of atom

A

-2pi^2mk^2e^4/h^2*n^2

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12
Q

frequency of emitted photon

A

h*mu=En2-En1

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13
Q

Rydberg formula for the spectrum of hydrogen series

A

wave number=r[1/(n1^2)-1/(n2^2)]
r->rydberg constant->1.0973
10^7 m^-1

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14
Q

lyman series

A

electron jumps from higher energy level to n=1 energy level
ultraviolet region
wave number=R[1/(1^2)-1/(n2^2)]

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15
Q

balmer series

A

electron from n=3,4,4,etc to n=2
visible region
wave number=R[1/(2^2)-1/n2^2]

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16
Q

paschen series

A

electron from n=4,5,,etc to n=3
infrared region
wave number =R[1/3^2-1/n2^2]

17
Q

brackett series

A

electron from n=5,6,etc to n=4
infrared region
wave number=R[1/4^2-1/n2^2]

18
Q

pfund series

A

electron from n=6,7,etc to n=5
infrared region
wave number=R[1/5^2-1/n2^2]

19
Q

limitation of bohr theory

A

-> This theory is only applicable for hydron-like series
-> Why only circular orbits not elliptical orbits
->electron has a wave nature so orbits of electrons are not defined
->does not explain the further splitting of spectral lines in a magnetic
and electric field

20
Q

excitaion energy

A

energy required to jump from lower to higher state

21
Q

ionisation energy

A

energy required to remove an electron from an atom

22
Q

relationship between kinetic energy and potential energy

A

P.E=-2 K.E