Atomic Theories Flashcards

1
Q

How did bohr expnd on rutherfords theory of the atom?

A

Quantized the shells

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2
Q

Electron ins ground state vs excited state

A

Ground has lower enegery

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3
Q

When an electron falls from higher engery level to lower enegry levels, how is energy released?

A

as a photon

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4
Q

Difference between previous model of atom vs modern quantum mechanical model?

A

2D vs 3D

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5
Q

Further from the nucleus the ____ energy an electron has.

A

More

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6
Q

region of space in which high probablity of finding an electron

A

Orbital

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7
Q

term used to label energy levels of electrons

A

n=

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8
Q

How are s orbitals different from p orbitals

A

different shape s =O p= 8

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9
Q

How does atom valence elctron configuration determine place on periodic table?

A

Valence determines block or group number

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10
Q

What two elements are exceptions to the way we normally write electron configurations? Write
the expected and the actual confi uration of each. What rules are followed? What ru es are
violated?

A

Cu= [Ar] 4s1 3d10
Cr= [Ar]4s0 3d5
full subshells are stable

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11
Q

Transition metals

A

titanium, chronium, mecury

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12
Q

Discovered the nucleaus

A

Ruther

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13
Q

Cathode ray tubes

A

Ruther

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14
Q

Discovered proton

A

Ruther

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15
Q

Most of atom empty space

A

Rutherford

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16
Q

Partial Positive

A

if something is a partial positive it’s electronegativity will be less than the other elements electronegativity
•if the molecule has more than two elements you look at the individual bonds

17
Q

Partial Negative

A

if something is a partial negative it’s electronegativity will be higher than the other elements

18
Q

Polar Bonds

A

to know if a molecule has polar or non-polar bonds you look at the difference in electronegativity
•if the difference is above 0.3 its polar bonds
•if the difference is below 0.3 its non-polar bonds

19
Q

Polar Molecules

A

to know if a molecule is polar or non-polar, you can look at its symmetry
•if its symmetrical the molecule is non-polar
•if its asymmetrical the molecule is polar

20
Q

London Forces

A

if the molecule is non-polar you will only have london forces

21
Q

Dipole Dipole

A

if the molecule is polar you will have dipole dipole forces (only if you don’t have hydrogen bonds)

22
Q

Hydrogen Bonds

A

if you only have a H with a 𝒮+and a N, O, or F with a 𝒮- you will have a hydrogen bond

23
Q

Density Formula

A

Mass/ Volume

24
Q

Ion

A

an atom that loses or gains electrons (to form a full valence shell) and results in a charge. It is a charged particle.

25
Q

Cations

A

lose electrons
become more positive

26
Q

Anions

A

gains electrons
becomes more negative

27
Q

Orbitals

A

3D space around a nucleus where there is a probability of finding electrons.

28
Q

S subshell

A

Principal Energy Level: +1
Shape: spherical
# of orbitals: 1
Max # of Electrons: 2

29
Q

P subshell

A

Principal Energy Level: +2
Shape: Dumbell like
# of orbitals: 3
Max # of Electrons: 6

30
Q

D subshells

A

Principal Energy Level: +3
Shape: vary
# of orbitals: 5
Max # of Electrons: 10

31
Q

F subshells

A

Principal Energy Level: +4
Shape: Vary
# of orbitals: 7
Max # of Electrons: 14

32
Q

Aufbau Principal

A

each electron is added to the lowest energy level available.

33
Q

Hund’s Rule

A

for orbitals at the same energy level, one electron occupies each sub orbital before the electrons pair up.

34
Q

Pauli Exclusion Principal

A

only two electrons (with opposite spins) can occupy each orbital

35
Q

Lewis Bonding Theory

A

atoms/ions are stable if they have an octet of electrons •electrons are most stable in pairs
•atoms form chemical bonds (ionic or covalent) to become stable

36
Q

VSEPR Theory

A

VSEPR (Valence Shell Electron Pair Repulsion)
•valence electrons stay as far away as possible to minimize repulsion
•when looking at a molecule we look specifically at the central atom (the one that has the most bonding electrons) to determine the 3-D geometry