atomic structure : the nucleus practice q Flashcards
symbol and mass number of atom with 3 less protons and 3 less neutrons compared to an atom of 27Al
21 Ne
10
why would there be 2 peaks of one metal on an abundance and m/z graph
2 isotopes
why would 2 ions have the same velocity and arrive at detector at same time
they have the same m/z charge
in mass spectrometer mr of each isotope is proportional to the current generated by that isotope at the detector
explain how current is generated
electrons transferred at the detector
from plate to + ion
explain how metal atom are ionised by electron impact in mass spectrometer
high energy electrons
fired at the atoms
from an electron gun
which knocks off 1 electron
the 1+ ions formed are accelerated using negatively charged electric plate
why is a negatively charged plate used
positively charged ions are attracted to negative plate
so velocity increases
name the order of the mass spectrometer
acceleration, ionisation, ion drift, detection
describe the process of electrospray ionisation
sample dissolved in a volatile solvent
injected through a needle at high voltage
gains a proton/ H+
explain how ions abundance is measured
ions reach the negatively charged plate
electrons flow from the plate to the positive ions
a current is produced, the size of the current is proportional to the abundance of the ion
what is used to accelerate ions in a mass spectrometer
negatively charged plate
Define relative atomic mass
the average mass of 1 atom of an element
on a scale in which an atom of 12C has a mass of 12
empirical formula
simplest whole number ratio of atoms of each element in a compound or molecule