Atomic structure - Mass spec c Flashcards
What is relative atomic mass
Average mass of an atom of an element compared to carbon 12
What is relative isotopic mass
Mass of an atom of an isotope of an element compared to an atom of carbon 12
What is relative molecular mass
Average mass of a molecule compared to 1/12 an atom of carbon 12
What are the four steps in a mass spectrometer
Acceleration
Ion drift
Ionisation
Detection
What happens during a acceleration
+ charged ions are accelerated by elec field and have the same KE
What happens during ion drift
The ions enter a region with no electric field so they drift through it and lighter ions will travel faster
What happens during Electron spray ionisation
The sample is dissolved
Pushed through a nozzle at a high pressure
High voltage caused each particle to gain H+ ion
The sample is turned into a gas made from + ions
What happens during electron impact ionisation
The sample is vaporised
An electron gun fires high energy electrons at it
Knocks an electron of so they become +1 ions
What happens during detection
Lighter ions travel at higher speeds, heavier ions are slower . The detector detects charged particles and when the ions hit the detector it generated a current which is directly proportional to the abundance