Atomic structure - Mass spec c Flashcards

1
Q

What is relative atomic mass

A

Average mass of an atom of an element compared to carbon 12

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is relative isotopic mass

A

Mass of an atom of an isotope of an element compared to an atom of carbon 12

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is relative molecular mass

A

Average mass of a molecule compared to 1/12 an atom of carbon 12

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What are the four steps in a mass spectrometer

A

Acceleration
Ion drift
Ionisation
Detection

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What happens during a acceleration

A

+ charged ions are accelerated by elec field and have the same KE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What happens during ion drift

A

The ions enter a region with no electric field so they drift through it and lighter ions will travel faster

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What happens during Electron spray ionisation

A

The sample is dissolved
Pushed through a nozzle at a high pressure
High voltage caused each particle to gain H+ ion
The sample is turned into a gas made from + ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What happens during electron impact ionisation

A

The sample is vaporised
An electron gun fires high energy electrons at it
Knocks an electron of so they become +1 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What happens during detection

A

Lighter ions travel at higher speeds, heavier ions are slower . The detector detects charged particles and when the ions hit the detector it generated a current which is directly proportional to the abundance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly