Atomic structure and radioactivity Flashcards
How large are atoms?
Very small, with a radius of about 1 × 10⁻¹⁰ m.
Describe the basic structure of an atom.
A positively charged nucleus
composed of both protons and neutrons surrounded by negatively charged electrons.
The radius of a nucleus is less than _______ of the radius of an atom.
1/10 000
Where is most of the mass of an atom concentrated?
In the nucleus.
Why are atoms neutral?
The positive charge from the protons cancels out the negative charge from the electrons.
How are the electrons of an atom arranged?
They orbit the nucleus at different distances from it (different energy levels).
How might electron arrangements change?
With the absorption or emission of electromagnetic radiation.
Explain what happens when atoms absorb electromagnetic radiation.
Electrons gain energy and can move to higher energy levels (further from the nucleus).
Explain what happens when atoms emit electromagnetic radiation.
Electrons lose energy and move down to lower energy levels (closer to the nucleus).
Atoms have no overall what?
electrical charge
What is the number of protons in an atom of an element called?
Its atomic number
What is the total number of protons and neutrons in an atom called?
Its mass number
How can atoms turn into ions?
If they lose one or more outer electron(s).
What are the ways in which electrons can leave an atom?
-Absorbing electromagnetic radiation of enough energy so that the outer electrons can escape the pull of the nucleus
-Being hit by a particle such as an alpha or beta particle
What are the types of electromagnetic radiation with enough energy to allow outer electrons to escape the pull of the nucleus?
-UV
-X-rays
-Gamma-rays
What might new experimental evidence lead to?
A scientific model being changed or replaced.
Before the discovery of the electron, what were atoms thought to be?
Tiny spheres that could not be divided.
What did the discovery of the electron lead to?
The Plum Pudding model (of the atom).
What dis the plum pudding model suggest that the atom is?
A ball of positive charge with negative electrons embedded in it.
What conclusions were drawn from the alpha particle scattering experiment?
-The mass of an atom was concentrated at the centre (in the nucleus).
-The nucleus was charged.
Which model replaced the Plum pudding model?
Rutherford’s nuclear model.
How did Niels Bohr adapt Rutherford’s nuclear model?
By suggesting that electrons orbit the nucleus at specific distances.
The theoretical calculations of Bohr agreed with (and helped explain) what?
Other scientists’ experimental observations at the time.
What did later experiments by Rutherford et al lead to? (after Bohr)
The idea that the positive charge of any
nucleus could be subdivided into a whole number of smaller particles.
And that each particle had the same amount of positive charge.
These particles were named protons.
What is a hydrogen nucleus?
A proton!
The experimental work of James Chadwick provided the evidence for what?
The existence of neutrons within the nucleus.
When did James Chadwick prove the existence of neutrons within the nucleus?
About 20 years after the nucleus became an accepted scientific idea.
What is the order of scientists who developed the atomic model?
-Dalton
-Thomson
-Rutherford
-Bohr
-Chadwick
Why was Rutherford expecting most of the alpha particles to pass straight through the thin sheet of gold foil? (or be very slightly deflected at most).
Because the positive charge of the atom was thought to be very ‘spread out’ through the ‘pudding’ of the atom.
What was the alpha particle scattering experiment?
Positively charged alpha particles were fired at an extremely thin sheet of gold foil.
Explain how Rutherford’s work led to the conclusion that atoms had a small, positive nucleus. (4)
Positive alpha particles were fired at the nucleus.
Most went through undeflected, so most of the atom must be empty space.
There is a small positive nucleus because very few of the alpha particles were deflected backwards.
Some were deflected more than expected because they came close to the concentrated, positively charged nucleus.
What is the problem with Rutherford’s nuclear model?
If electrons were in a ‘cloud’ around the nucleus of an atom, they should be attracted to the positive nucleus, causing them to rush inward and the atom to collapse.
How did Bohr overcome the problem of Rutherford’s model (collapsing atoms)
In 1913, he proposed that electrons orbit the nucleus in fixed shells, (no where in between) at a fixed distance from the nucleus, which kept the atom from collapsing.
What is the modern day model of the atom called?
The nuclear model.
Describe the differences between the nuclear model and the ‘plum pudding’ model of the atom. (pt 1)
-In the nuclear model, mass is concentrated at the centre of the atom (in the nucleus) , but in the plum pudding model, mass is evenly distributed.
-In the nuclear model, positive charge occupies only a small part of the atom, but in the plum pudding model, positive charge is spread throughout the atom.
Describe the differences between the nuclear model and the ‘plum pudding’ model of the atom. (pt 2)
-In the nuclear model, electrons orbit the nucleus at a fixed distance in shells, but in the plum pudding model, electrons are embedded in the mass of positive charge.
-In the nuclear model, the atom is mainly empty space, but the plum pudding model is a ‘solid’ mass.
Some atomic nuclei are…
unstable.
How do unstable nuclei change to become more stable?
They give out radiation.
This is a random process.
What is the name for the random process in which the nucleus of an atom gives out radiation as it changes to become more stable?
Radioactive decay.
Activity
The rate at which a source of unstable nuclei decays.
What is the unit for activity?
becquerel (Bq)
Count-rate
The number of decays recorded each second by a detector (eg Geiger-Muller tube).
How do we calculate activity?
Number of decays ÷ number of SECONDS
Explain how the activity of a source relates to how unstable its nuclei are.
A sample of a material with very unstable nuclei will have a high activity because many of the particles will decay each second.
Whereas a material with more stable nuclei will have a lower activity because fewer particles will decay each second.
Explain why the activity of a source decreases with time.
Activity is directly related to the number of unstable particles present at the time.
Over time, as more of the unstable nuclei decay and become stable, there are fewer unstable nuclei left.
So, the activity will decrease as fewer unstable nuclei are left to decay each second.
What is a Geiger-Muller tube?
A machine used to detect nuclear radiation.
It’s connected to a counter/ratemeter which shows the count rate.
If count rate decreases, the total amount of radiation absorbed by a material must…
…increase.
Number recorded on counter + The amount of radiation detected from the source + what?
Background radiation.
Why might an experiment be thought to be valid?
If measurements are made many times/ over a long period of time. (and have similar results).
Describe the model now used for the structure of an atom (6).
The nuclear model has:
-A small nucleus which is positively charged overall
-Protons and neutrons (both with a relative mass of 1) contained within the nucleus
-Protons have a relative charge of +1, whilst neutrons have a neutral charge (0)
-Negatively (-1) charged electrons which orbit the nucleus on electron shells
-Which are at fixed distances from the nucleus
What can nuclear radiation emitted be?
-An alpha particle (α)
-A beta particle (β)
-A gamma ray (γ)
-A neutron (n)
What is an alpha particle (α)?
-Two neutrons and two protons
-It is the same as a helium nucleus
-It has a mass number of 4
-It has an atomic (proton) number of 2
What is a beta particle (β)?
-A high speed electron ejected from the nucleus as a neutron turns into a proton
-It has a mass number of 0
-It has a charge of -1
What is a gamma ray (γ)?
- Electromagnetic radiation emitted from the nucleus
When an alpha particle is emitted, what effect does this have on the nucleus?
-Mass number is reduced by 4
-Positive charge (proton number) is reduced by 2
When a beta particle is emitted, what effect does this have on the nucleus?
-No change to the mass number
-Positive charge increases by 1 (atomic number)
When gamma rays are emitted, what effect does this have on the nucleus?
-It has no effect on either the mass or the charge of a nucleus as only energy (in the form of electromagnetic radiation ) is emitted.
When a neutron is emitted, what effect does this have on the nucleus?
-Mass number decreases by 1
-No change to the atomic (proton number)
When unstable elements undergo radioactive decay, what do they change into?
Other elements.
Ionising power of a neutron
Not directly ionising
Ionising power of an alpha particle
Very/highly ionising
Ionising power of a beta particle
Moderately ionising
Ionising power of gamma-rays
Weakly ionising
Range of alpha particles in air
around 5cm
Range of beta particles in air
a few metres
Range of gamma rays in air
a few kilometres
Penetration through materials - alpha particles
Can be stopped by a thin sheet of paper
Penetration through materials - beta particles
Can be stopped by aluminium 3mm thick
Penetration through materials - gamma rays
Can be stopped by thick lead or concrete
Doo neutrons have a high penetrating power?
Yes.
This is due to them having no charge and not interacting strongly with matter.
Neutrons can travel through ______ for long distances before being stopped.
Humans and buildings
How do alpha particles, beta particles, and gamma rays ionise atoms?
By colliding with them, causing them to lose electrons.
Explain why alpha particles are the most ionising radiation.
They have the greatest mass and the greatest charge, so can remove electrons more easily from the shells of atoms.
Explain why radioactive decay is a random process.
You cannot predict when a nucleus will decay by emitting radiation.
Explain why alpha particles are much more dangerous inside than outside the body.
Alpha particles are highly ionising and readily absorbed by nearby cells, which can lead to mutations when inside the body.
Outside the body, they have a very short range and are unlikely to reach the body and cause harm to cells.
State three uses of gamma rays (ionising radiation).
-To kill cancer cells (radiotherapy)
-To diagnose cancer (and other medical problems using tracers)
-To sterilise surgical equipment
-To preserve food
-In smoke alarms