Atomic Structure Flashcards
Atomic number is…?
Protons (and electrons)
Mass number is..?
Protons + neutrons (top part)
Isotopes
Same element with the same atomic atomic number but different mad number (neutrons)
Mass spectrometer parts ?
Ionisation (sample bombarded with electrons)
Acceleration(cations accelerated)
Deflection( ions deflected through a magnetic field- depended on m/z)
Detection( ions hit detector - current produced)
Relative atomic mass of isotopes
Total of abundance of isotopes
Electronic configuration exceptions?
They want to fill d orbital and half fill the 4s orbital
Cu- 1s2 2s2 2p6 3s2 3p6 3d10 4s1
Cr - 1s2 2s2 2p6 3s2 3p6 3d5 4s1
First ionisation energy
Energy required to convert 1 mole of gaseous atoms into 1 mole of gaseous cations, each atom losing an electron.
Ionisation energy trend?
Increase across period (generally)
Drop between 2 and 3 due to electron from 3p orbital ( which is higher in energy) is removed
Drop between 5 and 6 due to paired repulsion
First second and third ionisation energy half equation
Look them up need to know them