Atomic structure Flashcards
Relative Atomic Mass
The average mass of an atom of an element relative to 1/12th of the mass of 1 atom of carbon–12
Isotope
atoms of elements with the same number of protons and electrons but a different number of neutrons
relative isotopic mass
The average mass of an isotope of an element relative to 1/12th of the mass of 1 atom of carbon–12
First ionisation energy
the energy change when one mole of electrons is removed from one mole of gaseous atoms of that element.
State of elements in ionisation energy equation
gas
Aluminium first ionisation energy equation
Al(g) —-> Al+(g) + e-
1st ionisation energy …… down a group. Why?
decreases, due to shielding from other electrons as more shells and less nuclear attraction
1st ionisation energy …….. across a period. why?
Increases, due to higher nuclear charge with not much change in radius so electrons are pulled closer
what do jumps in successive ionisation energy show
new quantum shells
Max electrons on a shell formula
2n^2
Orbital
the region an electron occupies around an atom
s shape
spherical
p shape
dumb bell
d shape
double dumb bell
Periodicity
The repetition of properties of elements at repeated intervals across a period.
4 key concepts for periodicity
distance from nucleus, nuclear charge, shielding, paired electrons
atomic radius……. across a period. why?
decreases due to higher nuclear charge
atomic radius …….. down a group. why?
increases due to more electron shells
why are noble gases exempt from the atomic radius pattern across a period
They have a paired outer shell electron which repels causing a larger atomic radius
Isoelectronic
toms or ions that have the same electronic configuration as each other.
Excited electrons
Electron is being promoted from a lower to a higher energy level, Requires an input of energy, Energy is a fixed amount
emission spectrum
shows the frequencies of electromagnetic radiation that are emitted by a substance when electrons are returned to the ground state
absorption spectrum
shows the frequencies of electromagnetic radiation that are absorbed by a substance when electrons are promoted to higher energy levels