Atomic Orbitals And Quantum Numbers Flashcards

1
Q

How do we find the principal quantum number (n) of an element?

A

Look at the row number

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

When is the f sub shell introduced?

A

At n=6

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the electron configuration for Cr?

A

[Ar]4s^15d^6

(this is an exception!)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What happens to the atomic radii as we move across the periodic table?

A

It becomes smaller because the number of protons is greater

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What happens to the atomic radii as we move down atomic groups?

A

It becomes greater because the number of shells increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

When does ionic radii increase?

A

When the number of electrons increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

When does ionic radii decrease?

A

When the number of protons increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is electron affinity?

A

Energy released when an electron is added

Smaller EA harder to add

Larger EA easier to add electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

When are elements more likely to gain electrons?

A

As we move towards the right of the table (closer to the non-metallics)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Does electron affinity does increase or decrease as we move down the group?

A

It decreases

Higher on the group GREATER electron affinitiy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Do metallic elements lose or gain electrons?

A

Lose

Non-metallics GAIN electrons!

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is ionization energy?

A

Energy required to remove an electron

Larger IE harder to remove electrons
Smaller IE easier to remove

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why is ionization energy always positive?

A

We always apply energy to remove electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Do non-metallics have a high or low ionization energy?

A

High because they want to gain electrons, not lose them like metals

Metals have low ionization energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

As we move to the right of the table, does it take more energy to remove an electron?

A

Yes because the elements have more non-metallic characteristics

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Between K and Na, which has a higher ionization energy?

K atomic number- 19, Na atomic number- 11

A

Na because it is higher on the group

Down groups, the metallic energy increases which means the IE decrease

17
Q

Why does Be have a higher ionization energy than B?

Be: atomic number is 4, B: atomic number is 5

A

Be has a completely full s shell, so it requires more energy to remove an electron

This is an exception!

18
Q

Why does O have a higher ionization energy than N?

A

The shells of O are more stable than that of N.

THIS EXCEPTION ALSO APPLIES TO P AND S

19
Q

principal quantum number (n)

A

size and energy of the orbital (comes from row number)

20
Q

Angular momentum quantum number (l)

A

shape of atomic orbital (l= 0, …, n-1)

21
Q

Magnetic quantum number (ml)

A

orientation of the orbital in space relative to the other orbitals (ml= -l, …, 0,…,+l)

22
Q

Electron spin quantum number (ms)

A

Electron spin quantum number (ms =+/- 1/2)