AP bio Unit 3 Flashcards
redox reaction
A chemical reaction involving the transfer of one or more electrons from one reactant to another; also called oxidation-reduction reaction.
oxidized reactant in cellular respiration
glucose
reduced reactant in cellular respiration
Oxygen
purpose of cellular respiration
produce ATP
NAD+/NADH
an organic molecule that serves as an electron carrier by being oxidized (losing electrons) to NAD+ and reduced (gaining electrons) to NADH
Role of NAD+ in cellular respiration
the NAD+ picks up electrons from glucose and turns to NADH to transport them
glycolysis location
cytoplasm
link reaction location
mitochondrial matrix
Krebs cycle location
mitochondrial matrix
Electron transport chain location
inner mitochondrial membrane
oxidative phosphorylation
powered by the redox reactions of the electron transport chain
substrate-level phosphorylation
The formation of ATP by directly transferring a phosphate group to ADP from an intermediate substrate
inputs of glycolysis
Glucose, e-, ADP, Pi, H+, NAD+, ATP 2
outputs of glycolysis
2 pyruvate, ATP 4, NADH, H+, H2O
pyruvate oxidation
Conversion of pyruvate to acetyl CoA and CO2 that occurs in the mitochondrial matrix in the presence of O2.
Krebs cycle inputs
2 Acetyl CoA, 6 NAD+, 2 FAD, 2 ADP
Krebs cycle outputs
4 CO2, 6 NADH, 2 FADH2, 2 ATP
Krebs cycle purpose
make electron carriers NADH and FADH2 to move on to ETC
amount of ATP produced per glucose during cellular respiration
30 - 32
Oxidation and Reduction in ETC
-NADH is oxidized (loses e-)
-oxygen is reduced (gains e-)
Use of energy from ETC
creation of ATP
reason for double membrane in mitochondria
Hydrogen ions stored between membranes
How ATP is generated in the ETC
The hydrogen ions that went into the membrane from the electron transport chain are forced to leave through an enzyme called ATP synthase which creates ATP from ADP and phosphate with the energy from the hydrogen ions leaving.
Why cellular respiration is completed in steps
To maximize the usage of the energy being produced
Step of cellular respiration where glucose is completely oxidized
2 turns of the Krebs cycle
Steps of cellular respiration where oxygen is needed
Pyruvate oxidation and the Krebs cycle require oxygen to be present. Oxidative phosphorylation (ETC) requires oxygen as an input
final electron acceptor of ETC
oxygen which then creates water
Protein pumps in ETC
create the H+ gradient in ETC
Oxygen’s purpose in ETC
Very electronegative, pulls in the electrons at the end.
Enzyme
A protein that catalyzes chemical reactions.
Catalyst
A substance that speeds up a reaction without being consumed.
Substrate
The reactants that enzymes act upon.
Active Site
Region on enzyme where substrate binds.
Induced Fit Model
Enzyme changes shape to bind substrate better.
Competitive Inhibition
Inhibitor mimics substrate, blocking active site.
Noncompetitive Inhibition
Inhibitor binds elsewhere, changing enzyme shape.
Cofactors
Nonprotein helpers for enzyme activity.
Coenzymes
Organic cofactors that assist enzymes.
Energy Coupling
Using exergonic reactions to drive endergonic ones.
ATP
Energy carrier with three phosphate groups.
ADP
Adenosine diphosphate, lower energy form than ATP.
Substrate Level Phosphorylation
Direct transfer of phosphate to ADP from substrate.
Oxidative Phosphorylation
ATP production via electron transport chain reactions.
Glycolysis
Process breaking down glucose to pyruvate.
Krebs Cycle
Series of reactions producing electron carriers and CO2
Electron Carriers
Molecules that transport electrons in cellular respiration.
Fermentation
Anaerobic process converting sugars to acids or alcohol.
Photosynthesis
Process converting light energy into chemical energy.
Light Reactions
Convert solar energy into ATP and NADPH.
Calvin Cycle
Uses ATP and NADPH to synthesize glucose.
Carbon Fixation
Attachment of CO2 to RuBP in Calvin Cycle.
Rubisco
Enzyme catalyzing carbon fixation in photosynthesis. Most abundant enzyme on earth
G3P
Intermediate product in the Calvin Cycle. one is released at the end while 5 are kept in the cycle
Accessory Pigments
Molecules that capture additional light energy.
Chloroplast
Organelle where photosynthesis occurs.
Thylakoids
Membrane structures in chloroplasts for light reactions.
Stroma
Fluid in chloroplasts where Calvin Cycle occurs.
Absorption Spectrum
Wavelengths of light absorbed by chlorophyll.
pH in Thylakoid Space
Lowest due to high hydrogen ion concentration.
pH in Stroma
Highest due to lower hydrogen ion concentration.
ATP synthase
Enzyme facilitating ATP production via hydrogen ions.
Anthocyanins
Pigments responsible for red, purple, and blue colors in plants.
Xanthophylls
Yellow pigments that help in light absorption.
Chlorophyll breakdown
Process revealing accessory pigments during autumn.
Light reaction inputs and outputs
inputs - 2 H2O, 3 ADP, 3Pi, 2 NADP+; outputs - O2, 2 NADPH, 3 ATP
Calvin cycle inputs and outputs
inputs - 3 CO2, 9 ATP, 6 NADPH; outputs - 9 ADP, 6 NADP+, 6 H2O, 9 Pi
Photosynthesis Equation
6CO2 + 12H2O + light energy -> C6H12O6 + 6O2 + 6H2O
Oxidized Molecule in photosynthesis
Water (H2O) loses electrons during photosynthesis.
Reduced Molecule in photosynthesis
Carbon dioxide (CO2) gains electrons during photosynthesis.
Photosystem I (PSI)
Complex where light energy re-excites electrons for further transfer.
NADP+ in photosynthesis
Final electron acceptor in photosynthesis, forming NADPH.
PGA
3-carbon molecule formed during carbon fixation phase.
Aerobic Respiration
Oxygen-utilizing process generating maximum ATP.
Anaerobic Respiration
Oxygen-free process using metals as electron acceptors.
Oxidation and reduction in Glycolysis
glucose is oxidized and ADP is reduced
Exergonic Reactions
Reactions that release energy, regenerating ATP.
Metabolism
Totality of an organism’s chemical reactions.
Catabolism
Energy-releasing reactions that break down molecules.
Anabolism
Energy-requiring reactions that synthesize molecules.