ANALYSIS Flashcards
Outline the molecular ion formed equation
Molecular ion formed:
M > M+ + e-
Define molecular ion
The molecule with one electron knocked off
How can molecules with the same Mr be differentiated in a sample
Mass spectrometry
Precise
Acurate masses of atoms
What is a rogue absorption
Indication of impurity
Wrong absorption on infrared spectroscopy
Alkene testing
Bromine water
Orange to colourless
Aldehyde testing
Fehlings solution/Benedicts
Blue to red precipitate
Tollens reagent
Silver mirror forms
Carboxylic acid testing
Sodium carbonate
Effervescence of CO2
Primary/Secondary alcohol/aldehyde test
Sodium dichromate and sulphuric acid
Orange to green
Chloroalkane testing
Warm with silver nitrate
Slow formation of white AgCl precipitate
Outline the use of tollens reagent and how it’s made
Mixing aqueous ammonia and silver nitrate
Heat gently
Aldehydes are oxidised to form silver mirror
Outline the use of fehlings solution
Heat gently
Aldehydes are oxidise to form a red precipitate