Aminoacids, peptides and proteins Flashcards

1
Q

What is an amino acid?

A

A compound containing both an amine group and a carboxylic acid group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is an alpha amino acid?

A

The amine and carboxylic acid group are attached to the same carbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Which amino acids exhibit optical isomerism?

A

All except glycine (2-aminoethanoic acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Why do amino acids have a very high boiling point?

A

They naturally exist in their zwitter ion form. This can form ionic bonds which cause the high BP

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Why are amino acids amphoteric?

A

The amine group can act as a base and the carboxylic acid group can act as an acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why can amino acids form esters?

A

The carboxylic acid group can be hydrolysed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What are peptides?

A

Peptides are formed when multiple amino acids join together via a peptide linkage

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is a peptide linkage?

A

O=C
|
N-H

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What are protein polymers?

A

Polypeptides formed of multiple naturally occurring amino acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What are the structure of proteins?

A

1* - A simple sequence of amino acids
2- Proteins fold into alpha helixes or B pleated sheets with hydrogen bonds between them
3
- The protein as a whole coils and folds with respect to each of the other parts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What are condensation polymers?

A

Monomers joined together to produce a polymer and a small molecule e.g water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How are polyesters formed?

A

Condensation polymerisation of dioc carboxylic acids and diols

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is terylene formed from?

A

benzene, 1,4 dicarboxylic acid and ethan-1,2-diol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is polylactic acid made from?

A

2-hydroxypropanoic acid (lactic acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

How are polyamides formed?

A

Condensation polymerisation of dioc carboxylic acids and diamines

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is kevlar formed from?

A

benzene 1,4 dicarboxylic acid and benzene 1,4 diamine

17
Q

What is nylon 6,6 formed from?

A

hexandioic acid and hexane 1,6 diamine

18
Q

How is a peptide acid hydrolysed?

A

peptide + HCl gives 2 amino-acids with protonated amine groups (N-Cl-)

19
Q

How is a peptide base hydrolysed?

A

peptide + NaOH gives 2 amino acids where acid group become sodium salts