Amines Flashcards

1
Q

Nucleophilic subtitution

NH3 + RX —> RNH3+ X- + ? —> RNH2 + H20 + X-

A

OH-

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2
Q

If an excess of NH3 the reaction stop otherwise:

RNH2 + RX —> ?

A

(R)2NH2+ X-

mechanism : SN2

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3
Q

RX _ NaN3 —> ? + LiAlH4 —> ?

A
  1. RN3 2. RNH2
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4
Q

Benzene —> benzene - NO2 —> benzene - NH2

A
  1. HNO3 / H2So4 2. H2 Pt / C2H5OH

2. Sn, HCl

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5
Q

R-CN —(LiAlH4)—> ?

A

RCH2NH2

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6
Q

R C(=O)NH2 – LiAlH4–> ?

A

RCH2NH2

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7
Q

(R)2 C = O —?—> (R)2C = NH —(H2, Ni)—> ?

A
  1. NH3

2. (R)2CHNH2

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8
Q

RC(=O)NH2 —(NaOH,Br2 / H2O)-> ? + ?

A

RNH2 + CO2

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9
Q

Know the reaction of Arylamines (p.38)

A

yes

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10
Q

Know the sandmeyer reactions

A

yes

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