Amines Flashcards
1
Q
Nucleophilic subtitution
NH3 + RX —> RNH3+ X- + ? —> RNH2 + H20 + X-
A
OH-
2
Q
If an excess of NH3 the reaction stop otherwise:
RNH2 + RX —> ?
A
(R)2NH2+ X-
mechanism : SN2
3
Q
RX _ NaN3 —> ? + LiAlH4 —> ?
A
- RN3 2. RNH2
4
Q
Benzene —> benzene - NO2 —> benzene - NH2
A
- HNO3 / H2So4 2. H2 Pt / C2H5OH
2. Sn, HCl
5
Q
R-CN —(LiAlH4)—> ?
A
RCH2NH2
6
Q
R C(=O)NH2 – LiAlH4–> ?
A
RCH2NH2
7
Q
(R)2 C = O —?—> (R)2C = NH —(H2, Ni)—> ?
A
- NH3
2. (R)2CHNH2
8
Q
RC(=O)NH2 —(NaOH,Br2 / H2O)-> ? + ?
A
RNH2 + CO2
9
Q
Know the reaction of Arylamines (p.38)
A
yes
10
Q
Know the sandmeyer reactions
A
yes