Aldehydes and Ketones Flashcards

1
Q

Oxidation:
RCH2OH —> RCHO

CrO3 —> ?

A

PCC / CH2Cl2

carboxylic acid

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2
Q

Ozonolysis of alkenes:

(R)2 C = CHR —> (R)2 C = O + O = CHR

A
  1. O3

2. Zn/H2O

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3
Q

Friedel Crafts acylation:

R C (=O) Cl + benzene

A

AlCl3 — > benzene - c (=O)r

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4
Q

Hydration of Terminal Alkynes

CH3CH2CH2C (triple bond) CH —> CH3CH2CH2C(=O)CH3

A

H2O, H2SO4

HgSO4

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5
Q

CH3CO2C2H5 —> CH3CHO + C2H5OH

A
  1. DIBAH / toluene

2. H3O+

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6
Q

Gilman reagent

CH3CH2C(=O)Cl + ? —> CH3CH2C(=o) CH2CH3

A

(CH3CH2)2 Cu- Li+

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7
Q

The wittig reaction

A

know it

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