Aldehydes and Ketones Flashcards
1
Q
Oxidation:
RCH2OH —> RCHO
CrO3 —> ?
A
PCC / CH2Cl2
carboxylic acid
2
Q
Ozonolysis of alkenes:
(R)2 C = CHR —> (R)2 C = O + O = CHR
A
- O3
2. Zn/H2O
3
Q
Friedel Crafts acylation:
R C (=O) Cl + benzene
A
AlCl3 — > benzene - c (=O)r
4
Q
Hydration of Terminal Alkynes
CH3CH2CH2C (triple bond) CH —> CH3CH2CH2C(=O)CH3
A
H2O, H2SO4
HgSO4
5
Q
CH3CO2C2H5 —> CH3CHO + C2H5OH
A
- DIBAH / toluene
2. H3O+
6
Q
Gilman reagent
CH3CH2C(=O)Cl + ? —> CH3CH2C(=o) CH2CH3
A
(CH3CH2)2 Cu- Li+
7
Q
The wittig reaction
A
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