Alcohols Flashcards by Marie-Ève Thellend | Brainscape

Q

Hydration of Alkenes:

(CH3)2C = CHCH3 —> CH3)2C (OH) CH2CH3

A

H20 / H2SO4

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Q

HYdroboration-oxidation of Alkene:

(CH3)2 C = CHCH3 —> (CH3)2CHCH(OH)CH3

A

BH3/THF

2. H2O2/OH-

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Q

Reduction of Carbonyl compounds

CH3CH2CHO —> CH3CH2CH2OH

A

NaBH4, C2H5OH
H3O+
or
LiAlH4/ether
H3O+

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Q

Reduction of carboxylic acids

CH3CH2CO2H —> CH3CH2CH2OH

A

LiAlH4/ether

2. H3O+

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Q

Reduction of esterr with LiAlH4:

CH3CO2C2H5 —> ?

A

2 CH3CH2OH

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Q

Addition of Grignard reagent:

R-X —> RMgX

A

Mg / ether

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Q

Dehydration of alcohols to give alkenes:

(CH3)3 COH —> (CH3)2 C = CH2

A

H2SO4 / H3PO4

Heat

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Q

ANTIPERIPLANAR FASHION:

(CH3CH2)3 COH —> (CH3CH2)2 C = CHCH3

A

POCl3 / pyridine

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Q

ROH —> 1. RBr 2. RCl

A

PBr3 2. SOCl2

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