Alternative Fuels Flashcards
Diesel
C9 to C11
Petrol
C7 to C8 hydrocarbons
Paraffin
C12 to C16
Characteristic of replacements?
Renewable sources need to burn ŵith similar rate
Which molecule has highest and lowest energy?
Hydrogen highest, CO lowest
Brazil cars
100% ethanol from sugar cane used, 30% less CO produced, HCs levels same, ethanol unreactive in photochemical smogs
Consequence of lower oil prices
Less use of ethanol
USA
Plants exist to make ethanol, blending petrol from corn/grain
Oxyfuels
Petrol + methanol/ethanol/MTBE (methyl tertiary butyl ethane), improve combustion, less u burnt HCs, more CO to CO2 conversions
Problems
More carcinogens produced, PAN toxic to plants and cause gene mutations
Rapeseed Methyl Esther
Renewable replacement for diesel, few sooty particles, no SOx
Haly produced
22p/l compared to diesel 10p/l, no net CO2 contribution to atmosphere, CO2 released from taken in by plants
Vegetable oils and animal fats
Triglycerides, by-products of glycerol, chars, clogs-engines
Treatments
Oil with alkali (acid is released), react with methanol to form methyl ester, volatile
Britain
Sugar beet but takes 1/3 size of Wales which is unlikely, large reserves of fossil fuels