Alkenes Flashcards

1
Q

Are Alkenes Saturated or unsaturated

A

UNsaturated

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2
Q

How do Alkenes bond (description)

A

SP2 hybridisation = sigma bond, and left over p orbitals form a pi-bond,

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3
Q

Functional Group of Alkenes

A

C=C

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4
Q

what is an E isomer

A

large groups on opposite sides

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5
Q

Name all electrophilic addition reactions for alkenes

A

Hydrogenation
Hydration
Halogenation

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6
Q

Explain Hydrogenation of alkene in detail

A

Alkene + Hydrogen –> Alkane
the pi bond breaks and Hs joins
Needs Ni catalyst

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7
Q

Explain Hydration of alkene in detail

A

Alkene + Steam —> Alcohol
Phosphoric acid catalyst

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8
Q

Explain Halogenation of alkene in detail

A

Alkene + HX or X2 —> haloalkane or dihaloalkane
pi-bond breaks and halogen(s) (and/or H) joins on

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9
Q

Explain Addition polymerisation of an alkene

A

monomers are around the C=C,
C=C breaks and connects to other monomers

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10
Q

First alkene

A

LOL trick question not one

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11
Q

Second Alkene

A

Ethene

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12
Q

Propene + Cl2. —->

A

1,2 di chloro propane

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13
Q

During hetrolytic fission what happens

A

both electrons go to the atom with the delta negitive

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14
Q

Explain Homolytic fission

A

One elctron goes to each,
Free radical forms

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15
Q

which is stronger pi or sigma bond

A

sigma bond, pi bond breaks first

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16
Q

what reaction types do alkenes do

A
  • Electrophilic addition
    -Addition Polymerisation
17
Q

what is a Z isomer

A

BIG group on same side

18
Q

why can alkenes create isomers

A

C=C can’t rotate

19
Q

catalyst needed when alkene forms alcohol

A

acid catalyst (such as phosophoric)

20
Q

Conditions needed for when alkene forms alkane

A

Ni catalyst
high pressure and temp

21
Q

conditions needed for alkene –> alcohol

A

acid catalyist (phosphoric)
high temp and pressure

22
Q

according to makinokovs rule which is major product

A

one where the halogen is on the C with most alkyl groups (attached to Cs not H)

23
Q

General formula of Alkenes

A

CnH2n

24
Q

shape and angle of C=C

A

120 and trigonal planr

25
Q

are alkenes more or less reactive than alkanes

A

more as the high e- density of pi-bond and its easier to break than a sigma