Alkenes Flashcards
What is an alkene?
Unsaturated hydrocarbons with a C=C double bond
What is the general formula of an alkene?
Cn H2n
Why is there no rotation about the C=C double bond?
Due to the π (pi) orbital - electron density above and below the single bond, which holds the carbon atoms in place.
Are they more or less reactive than alkanes? Why?
More reactive, due to high electron density of double bond and the fact the pi-bond is slightly easier to break.
What intermolecular forces of attraction do they have?
Only van der Waals due to non-polar bonds
Are they soluble in water? Why?
No, non-polar bonds (van der Waals’ < hydrogen bonding)
Name and describe the three kinds of isomers alkenes can have
Chain isomers (branched chains).
Position isomers (C=C on different carbon atom).
Geometric E-Z isomers (Z is when 2 highest atomic number chains are on the same side of the double bond; E is when they’re on opposite sides)
Write an equation for the complete combustion of pent-2-ene.
CH3CH=CHCH2CH3 + 7½O2 → 5CO2 + 5H2O
What is an electrophile?
Electron deficient atoms/ions which accept a pair of electrons (here, from the C=C double bond)
What is the most stable kind of carbocation intermediate? Why?
Alkyl groups have a positive inductive effect, so the most stable carbonation is the one bonded to the most other carbon atoms i.e. A tertiary carbocation
Major products will be formed from which kinds of carbocations?
Tertiary (or the most stable available)
What conditions are needed for the electrophilic addition of H2O to an alkene?
Acid catalyst, usually phosphoric acid
What are the product(s) of the reaction?
An alcohol
What conditions are needed for the electrophilic addition of a hydrogen halide to an alkene?
Room temperature
What conditions are needed for the electrophilic addition of a halogen molecule to an alkene?
Room temperature and organic solvent