Alkanes and alkenes Flashcards

1
Q

What type of compounds are alkanes and alkenes?

A
  • Covalent compounds

- bond formed btwn non-metals

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2
Q

Physical properties of alkanes and alkenes

A
  1. Low MP/BP
  2. Insoluble in water
  3. Soluble in organic solvents
  4. Do not conduct electricity in any state
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3
Q

How physical properties change going down the series

A
  1. MP/BP increase
    - larger molecular size
    - stronger intermolecular forces
  2. More viscous
  3. Densities increase
  4. Flammability decreases
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4
Q

How physical properties change going down the series

A
  1. MP/BP increase
    - larger molecular size
    - stronger intermolecular forces
  2. More viscous
  3. Densities increase
  4. Flammability decreases
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5
Q

Why alkenes burn with smokier flame

A
  • Alkenes have higher percentage of carbon
  • Need more O2 for complete combustion
  • Higher chance of incomplete combustion, more carbon left as soot, smokier flame
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6
Q

Chemical Properties of Alkanes

A
  1. Generally unreactive
  2. Combustion
  3. Substitution rxn
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7
Q

Why are alkanes generally unreactive

A
  • consists of only C-C bonds (Single), C-H bonds

- bonds are strong, difficult to overcome

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8
Q

Combustion (Alkanes)

A
  • ignited by spark/flame
  • burn readily in xs air
  • produce CO2 and water vapour
  • highly exothermic
  • alkanes –> gd fuels
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9
Q

Substitution rxns

A
  • alkanes react with halogens
  • e.g. chlorine, bromine
  • presence of UV light
  • methane + chlorine –> chloromethane + hydrogen chloride
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10
Q

Cracking

A
  • breaking down of long-chain hydrocarbons

- into smaller molecules

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11
Q

Products of cracking

A
  1. Small alkanes
  2. Small alkenes
  3. Hydrogen gas
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11
Q

Products of cracking

A
  1. Small alkanes
  2. Small alkenes
  3. Hydrogen gas
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12
Q

2 ways of cracking

A
  1. Big alkane –> small alkane + small alkene

2. Big alkane –> small alkene + H2

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13
Q

Uses of cracking

A
  1. Produce smaller chain of alkenes (starting materials for alcohols, plastics)
  2. Produce H2 needed for fertilisers
  3. Produce petrol frm lubricating oil and diesel, more useful, higher demand
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14
Q

Evidence of cracking

A
  • bubbles of gas/effervescence

- shows liquid pertoleum (higher bp) converted into smaller alkanes and alkenes (lower bp)

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15
Q

Chemical properties of alkenes

A
  1. Addition of hydrogen/Hydrogenation
  2. Addition of Bromine/Bromination
  3. Addition of steam/Hydration
  4. Addition polymerisation
16
Q

Hydrogenation (Alkenes)

A
  • 200 degrees
  • presence of catalyst ie. nickel
  • alkenes react with hydrogen, form alkanes
17
Q

Bromination (Alkenes)

A
  • bromine soln = reddish brown
  • alkene + bromine –> decolourizes immediately, colourless liquid formed
  • alkane formed
18
Q

Hydration (Alkenes)

A
  • react with steam, produce alcohols
  • 300 degrees
  • 60 atm
  • phosphoric acid H3PO4 catalyst
19
Q

Addition polymerisation (Alkenes)

A
  • high temp and pressure
  • presence of catalyst
  • ethane molecules react w each other
  • form long molecule called polyethene
  • draw out structural formula
20
Q

Fats and Oils

A
  • some are polyunsaturated

- hydrocarbon chains contain more than 1 C=C bond