Alkanes Flashcards

1
Q

What is the general formula for alkanes?

A

CnH2n+2

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2
Q

Are alkanes saturated or unsaturated?

A

They are saturated.

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3
Q

What is the shape of alkanes?

A

Tetrahedral

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4
Q

How many pairs of bonding electrons surround each carbon atom?

A

4

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5
Q

How do the bonding electrons repel each other?

A

They repel each other equally.

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6
Q

What is the bond angle of alkanes?

A

109.5

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7
Q

What are the properties of short alkanes?

A

Low boiling point

Gases at RTP

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8
Q

In what state are larger alkanes?

A

They are liquids.

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9
Q

What type of bonds are inside alkane molecules?

A

Covalent bonds.

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10
Q

What type of bonds are between the alkane molecules?

A

London forces

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11
Q

What do the London forces do to the molecules?

A

They hold them all together.

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12
Q

What increases the strength of the London forces?

A

The longer the carbon chain,the stronger the induced dipole-dipole interactions.

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13
Q

Why do the induced dipole-dipole interactions get stronger as the carbon chain gets longer?

A

There is more surface contact and more electrons to interact.

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14
Q

Why does the boiling point rise as the carbon chain gets longer?

A

It takes more energy to overcome the London forces.

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15
Q

Why do branched-chain alkanes have lower boiling points than their straight-chain isomers?

A

They can’t pack together as closely so there is a smaller molecular surface area, this reduces the strength of the London forces.

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16
Q

What happens if you oxidise alkanes?

A

You get carbon dioxide and water.

17
Q

Do alkanes react completely in oxygen?

A

Yes

18
Q

In what state do the combustion reactions of alkanes occur?

A

In gas.

19
Q

What needs to happen to liquid alkanes before combustion?

A

They need to be vaporised.

20
Q

What burns more easily, long chain alkanes or short chain alkanes?

A

Short chain alkanes as they are gases.

21
Q

What is more volatile, long chain alkanes or short chain alkanes?

A

Short chain alkanes.

22
Q

Why do larger alkanes release more energy per mole?

A

They have more bonds to react.

23
Q

Why do alkanes make excellent fuels?

A

They release lots of energy when they burn.

24
Q

What do all gases at the same temperature and pressure have in common?

A

Thy have the same molar volume when at the same temperature and pressure.

25
Q

What can you use to calculate the molar ratios when atoms are at the same temperature and pressure?

A

You can use the ratio of the volumes of the gases reacting.

26
Q

What happens as a result of incomplete combustion?

A

Carbon monoxide and water is formed.

27
Q

What is the problem with carbon monoxide?

A

It binds to the haemoglobin before the oxygen can, this means that less oxygen is carried around in the body and therefore you can get oxygen deprivation.