Alkanes Flashcards

1
Q

What are alkanes?

A

Alkanes are saturated hydrocarbons

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2
Q

Why are alkanes considered saturated hydrocarbons

A

This is because all the carbon atoms are bonded with single bonds and there are no double or triple bonds

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2
Q

What are the primary uses of alkanes?

A

Alkanes are used as fuels, lubricants and as starting materials for the production of a wide range of other compounds

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3
Q

What is the main source of alkanes?

A

The main source of alkanes is crude oil

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4
Q

What is the general formula for alkanes?

A

The general formula for all chain alkanes is CnH2n+2

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5
Q

Why are unbranched alkanes not actually straight?

A

The C - C - C bond angle is 109.5 degrees, which gives the chain a zigzag shape rather than a straight line

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6
Q

Why are alkanes considered almost non - polar?

A

Alkanes are almost non - polar because the electronegativities of carbon (2.5) and hydrogen (2.1) are very similar

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6
Q

How does the size of an alkane molecule affect the strength of van der Waals forces?

A

The larger the alkane molecule, the stronger the van der Waal forces

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7
Q

Hw does the weak polarity of alkanes affect their physical properties?

A

The weak van der Waals forces lead to low boiling and melting points compared to more polar molecules of similar size

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8
Q

What is the relationship between molecular size and boiling point in alkanes>

A

As molecular size increases, the boiling points of alkanes increases due to stronger van der Waals

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9
Q

Why do the boiling points of alkanes increase as the chain length increases?

A

As chain length increases, the intermolecular van der Waals forces become stronger, requiring more energy to overcome

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10
Q

What state are shorter chain alkanes at room temperature?

A

Shorter chain alkanes are gases at room temperature

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11
Q

At what chain length do alkanes become solids at room temperature?

A

Alkanes with about 8 carbon atoms become solids at room temperature

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12
Q

How do the boiling points of branched alkanes compare to straight chain alkanes with the same number of carbon atoms?

A

Branched alkanes have lower boiling points than straight chain alkanes with the same number of carbon atoms

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13
Q

Why do branched alkanes have lower boiling points than unbranched alkanes?

A

branched alkanes cannot pack as closely together, making the van der Waals forces less effective

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14
Q

Why are alkanes insoluble in water?

A

Water molecules are held together by strong hydrogen bonds, which are much stronger than the van der Waals forces acting between alkane molecules

15
Q

What type of liquids do alkanes mix well with?

A

Alkanes mix with other relatively non - polar liquids

16
Q

Why are alkanes relatively unreactive?

A

Alkanes have strong carbon - carbon and carbon - hydrogen single bonds, which require a lot of energy to break