Alkanes Flashcards

1
Q

What is an alkane?

A
  • a saturated hydrocarbon containing C-H bonds only
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2
Q

Are their bonds polar? Why/why not?

A
  • non polar
  • carbon and hydrogen have similar electronegativities
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3
Q

Which intermolecular forces do they have?

A
  • only van de waals forces as bonds are non polar
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4
Q

Are they soluble in water? why?

A
  • insoluble because they have no polar bonds
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5
Q

How reactive are alkanes?

A
  • very unreactive
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6
Q

Which reactions will alkanes undergo?

A
  • combustion and reaction with halogen
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7
Q

What is crude oil? How is it formed?

A
  • mixture of hydrocarbons with similar boiling points
  • formed at high temperatures and pressures deep below earth surface over millions of years (non renewable)
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8
Q

What is fractional distillation and how does it work?

A
  • crude oil is heated until mostly vaporised
  • passed into a fractionating tower that is cooler at the top than the bottom
  • vapours rise up the column and condense at the fraction that is at the temperature of their boiling points
  • shortest chain hydrocarbons condense at the top as they have the lowest boiling points
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9
Q

What is cracking and why is it done?

A
  • process of turning a long chain alkane into a shorter chain alkane
  • shorter chain alkanes are more economically valuable
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10
Q

What are the conditions for thermal cracking?

A
  • 700 - 1200K
  • up to 7000kPa
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11
Q

What are the conditions for catalytic cracking?

A
  • lower temp
  • lower pressure
  • zeolite catalyst
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12
Q

What are the main products of catalytic cracking?

A
  • cycloalkanes, aromatic hydrocarbons, branched alkanes
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13
Q

What is incomplete combustion and what products are formed in the case of alkanes?

A
  • combustion a limited supply of oxygen
  • CO - carbon monoxide - poisonous
  • C - carbon - particulates - soot - global dimming
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14
Q

Which type of hydrocarbons are most likely to undergo incomplete combustion?

A
  • longer chains
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15
Q

What is the environmental impact of carbon monoxide?

A
  • it is toxic/poisonous
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16
Q

What is the environmental impact of nitrogen oxides?

A
  • form nitric acid - acid rain
  • smog
17
Q

What is the environmental impact of sulfur impurities/ sulfur dioxide?

A
  • forms sulfuric acid - acid rain
18
Q

What is the environmental impact of unburnt hydrocarbons?

A
  • photochemical smog
19
Q

What is the environmental impact of carbon dioxide?

A
  • greenhouse gas → global warming
  • increases global temperatures
  • speeds up climate change
20
Q

What are flue gases?

A
  • gases given out by power stations
21
Q

Write two equations for two different ways of desulfurising flue gases.

A
  • CaO (s) + 2H₂O (l) + SO₂ (g) + ½O₂ (g) → CaSO₄.2H₂O (s)
  • CaCO₃ (s) + SO₂ (g) + ½O₂ (g) → CaSO₄ (s) + CO₂ (g)
22
Q

What are catalytic converters made up of?

A
  • ceramic honeycomb coated with platinum, palladium and rhodium metals
23
Q

What are greenhouse gases?

A
  • gases which trap infrared radiation
  • making the earth act like a greenhouse
24
Q

How are halogenalkanes formed from alkanes?

A
  • free radical substitution reaction
25
Q

What are the three stages of free radical substitution?

A
  • initiation, breaking halogen bond to form free radicals
  • propagation - chain part of the reaction where products are formed but free radical remains
  • termination - free radicals removed, stable products formed
26
Q

What are the conditions needed for the formation of a free radical?

A
  • UV light
27
Q

Write equations for the reaction of CH₄ with Cl₂ to form CH₃Cl?

A
  • Initiation:
    Cl₂ → 2Cl*
  • Propagation:
    Cl* + CH₄ → CH₃
    CH₃ + Cl₂ → CH₃Cl + Cl
    Termination:
    CH₃ + Cl → CH₃Cl
    2Cl
    → Cl₂
    *CH₃ + *CH₃ → CH₃CH₃
28
Q

What is the ozone layers function?

A
  • protects the earth from harmful exposure to too many UV rays
29
Q

How do CFCs break the ozone layer down?

A
  • free radical substitution
30
Q

Write an equation for the overall decomposition of ozone into oxygen.

A
  • 2O₃ → 3O₂
31
Q

Write the free radical equations to show how Cl free radicals catalyse the decomposition of O₃.

A
  • Cl₂ → 2Cl*
  • Cl* + O₃ → ClO* + O₂
  • ClO* + O₃ → 2O₂ + Cl*
32
Q
A