Aldehydes and Ketones I Flashcards
carbonyl
double bond between a carbon and oxygen
pyridinium chlorochromate (PCC)
only reagent that can oxidate a primary alcohol to an aldehyde
geminal diols
aldehyde/ketones react with water to form these
hemiacetal/hemiketal
when an aldehyde or a ketone is attacked by an alcohol, it will attach and make the carbonyl into an alcohol
acetal/ketal
when attacked with more alcohol, the carbonyl is completely replaced
imine
nitrogen atom double bonded to a carbon
enamine
compound with a double bond and a nitrogen
cyanohydrin
-OH and -CN group
formation of carboxylic acid from aldehyde
performed by any oxidizing agent stronger than PCC: KMnO4, CrO3, Ag2O, H2O2
hydride reagents
turn aldehydes and ketones into alcohols; LiAlH4 NaBH$