Aldehydes and Ketones I Flashcards

1
Q

carbonyl

A

double bond between a carbon and oxygen

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2
Q

pyridinium chlorochromate (PCC)

A

only reagent that can oxidate a primary alcohol to an aldehyde

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3
Q

geminal diols

A

aldehyde/ketones react with water to form these

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4
Q

hemiacetal/hemiketal

A

when an aldehyde or a ketone is attacked by an alcohol, it will attach and make the carbonyl into an alcohol

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5
Q

acetal/ketal

A

when attacked with more alcohol, the carbonyl is completely replaced

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6
Q

imine

A

nitrogen atom double bonded to a carbon

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7
Q

enamine

A

compound with a double bond and a nitrogen

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8
Q

cyanohydrin

A

-OH and -CN group

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9
Q

formation of carboxylic acid from aldehyde

A

performed by any oxidizing agent stronger than PCC: KMnO4, CrO3, Ag2O, H2O2

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10
Q

hydride reagents

A

turn aldehydes and ketones into alcohols; LiAlH4 NaBH$

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