Alcohols Flashcards
What is the general formula?
CnH2n+1OH
What is the bond angle in the C - O - H bond ?
105
the 109.5 angle of a tetrahedron is reduced due to the presencence of lone pairs
lone pairs will repel each other more than the pair of electrons in a covalent bond
How many lone pairs does the O have?
2
What is a primary alcohol?
the -OH group has one R group
the carbon has 2 hydrogen atoms
-OH group at the end of the chain
What is a secondary alcohol?
the -OH group is attached to a carbon with 2 R groups
the carbon has one hydrogen atom
-OH group is in the body of the chain
What is a tertiary alcohol?
3 R groups attached to the carbon that is bonded to the -OH
the carbon has no hydrogen atom
the -OH group is at a brach in the chain
What are the physical properties of an alcohol?
hydrogen bonding occurs
melting point is higher than alkanes of a similar molecular mass
the -OH group of alcohols can hydrogen bond to water molecules but the non-polar hydrocarbon chain cannot
short chains are soluble long chains are not