alcohols Flashcards

1
Q

What can ethanol be used as

A

Biofuel

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2
Q

What is the formula for aldehydes

A

RCHO

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3
Q

What is the formula for ketones

A

RCOR’

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4
Q

What is the formula for a carboxylic acid

A

RCOOH

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5
Q

How can alcohols be classified

A

Primary - 1
Secondary - 2
Tertiary - 3

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6
Q

What does an aldehyde look like

What is the suffix
Name an example

A

R — C = O & the bottom — H

“al”
Ethanal

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7
Q

What does a ketone look like

What is the suffix
Name an example

A

Two R’s from the bottom of the c — R x2
=O from the top of the C

“One “
Propanone

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8
Q

What does an aldehyde look like

What is the suffix
Name an example

A

R — C =O from the top — OH from the bottom

“Oic acid”
Ethanoic acid

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9
Q

What can ethanol be used for

A

As an intermediate in the synthesis of other organic chemicals
As a solvent in cosmetics & perfumes
In the manufacture of drugs, detergents and inks
The alcohol in alcoholic drinks

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10
Q

What is a biofuel

A

A fuel produced from plants

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11
Q

What are the two seperation techniques for alcohols

A

Reflux
Distillation

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12
Q

Why are anti-bumping granules added to the flask in both distillation and reflux

A

to prevent vigorous, uneven boiling by making small bubbles form instead of large bubbles

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13
Q

What are the advantages and disadvantages of fermentation

A

Advantages
•sugar is a renewable resource
•production uses low level technology / cheap equipment

Disadvantages
•batch process which is slow and gives high production costs
•ethanol made is not pure and needs purifying by fractional distillation
•depletes land used for growing food crops

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14
Q

What are the advantages & disadvantages

A

Advantages:
•faster reaction
•purer product
•continuous process (which means cheaper manpower)

Disadvantages:
•high technology equipment needed (expensive initial costs)
•ethene is non-renewable resource (will become more expensive when raw materials run out) •high energy costs for pumping to produce high pressures

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15
Q

Oxidation of a 1 alcohol to an aldehyde

Reaction
Reagents
Observations
Conditions

A

Reaction - oxidation
Reagents - acidified potassium dichromate (KrCr2O7)
Observations - orange -> green
Conditions - Heat under distillation

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16
Q

Oxidation of a 1 alcohol to a carboxylic acid

Reaction
Reagents
Observations
Conditions

A

Reaction - reflux
Reagents - potassium dichromate (KrCrO7)
Observations - orange -> green
Conditions - reflux under heat

17
Q

Oxidation of a 2 Alcohol to a Ketone

Reaction
Reagents
Observations
Conditions

A

Reaction - Oxidation
Reagents - acidified potassium dichromate
Observations - orange -> green
Conditions - reflux or distillation

18
Q

For the following reagents,write the observation and state the functional group

Acidified KrCrO7
Fehlings solution
Tollen’s reagent
Na2CO3
Br2 water

A

Acidified KrCrO7 - orange -> green = 1 OH, 2 OH, aldehyde

Fehlings solution - brick red ppts form = Aldehyde

Tollen’s reagent - silver mirror forms = aldehydes

Na2CO3 - effervescence = carboxylic acids

Br2 water - orange -> colourless = alkenes