Advanced Theories Of Covalent Bonding Flashcards
How are pi bonds characterized
side-to-side overlap
When there are multiple bonds how many are sigma bonds and how many are pi?
One of the bonds is sigma and the rest are pi
How are sigma bonds characterized
Head-head overlap
What angle and hybridization is linear
180 degrees, sp hybridization
Trigonal planar angle and hybridization
120 degrees, sp^2
Tetrahedral angle and hybrization
109.5 degrees, sp^3
What happens to lattice energy when Q1 x Q2 increases?
Lattice energy increases
Is breaking bonds an exothermic process or endothermic process? And would the value of H be - or +
Breaking bonds takes up energy so the H value is positive. It is an endothermic process
When forming chemical bonds is it an exothermic or endothermic process? And is the H value + or -
Forming chemical bonds releases energy so the H value is negative. It’s an exothermic process
Bond enthalpy
How much energy is required to break a bond
First ionization energy trend
Increases as you go up and right on the periodic table
Sp^3d
Trigonal bipyramidal
Sp^3d^2
Octahedral