Adsorption Flashcards

1
Q

concentration of a substance on the surface of a solid or a liquid

A

adsorption

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2
Q

substance attracted to a surface

A

absorbate phase

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3
Q

substance to which it is attached

A

absorbent

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4
Q

factors that determined the amt of gas adsorbed by a solid

A
  1. nature of adsorbent and gas na inaabsorbed by a solid
  2. area of absorbent
  3. temperature of the gas
  4. pressure of the gas
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5
Q

Types of adsorption

A
  1. physical or van der waal’s adsorption
  2. chemical or activated adsorption or chemisorption
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6
Q

occurs when the intermolecular
forces of attraction between the fluid molecules and the solid surface are greater than the attractive forces between molecules of the fluid itself.

A

Physical or Van Der Waal’s Adsorption

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7
Q

Fluid molecules adhere to the surface of the solid adsorbent. The forces responsible for the adsorption are of the same fluid as are involved in the deviation of gases ideal behavior and in liquefaction, i.e. Van der Waal’s forces.

-characterized by low heats of adsorption.

A

Physical or Van Der Waal’s Adsorption

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8
Q

involves chemical interaction between the adsorbed fluid and the adsorbent solid.

A

Chemical or Activated Adsorption or Chemisorption

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9
Q

The adsorption is irreversible and it is difficult to separate the adsorbate from the adsorbent. Hence, only physical adsorption tends itself to continuous stage-wise operations.

A

Chemical or Activated Adsorption or Chemisorption

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10
Q

The ____________________ relates the concentration of the adsorbate in the solution and the adsorbate on the adsorbent at equilibrium at a given temperature.

A

Freundlich Isotherm

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11
Q

this has binding site where particles come in and there is chemical reaction

A

chemical adsorption

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12
Q

Freundlich Equation applies to adsorption of solute from

A

dilute solutions, over a small concentration range

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13
Q

In case of physical adsorption, the difference between heat of adsorption and heat of normal condensation is

A

equal to the heat of wetting

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14
Q

CO2 can be adsorbed by

A

heated charcoal

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15
Q

lon exchange process is similar to

A

adsorption

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16
Q

As complete saturation of an adsorbent is approached, the differential heat of
adsorption approaches

A

heat of normal condensation

17
Q

The change in enthalpy when a unit quantity of gas is adsorbed by a relatively large quantity of adsorbent (on which a definite concentration of the adsorbed gas already exists) is termed as the

A

differential heat of adsorption

18
Q

With an increase in concentration of the adsorbate the integral heat of adsorption

A

decreases

19
Q

The change in enthalpy per unit weight of adsorbed gas when adsorbed on a gas-free or “outgassed” adsorbent to form a definite concentration of adsorbate is called its

A

integral heat of adsorption

20
Q

In physical adsorption, a gas of

A

higher molecular weight is adsorbed in preference to a gas of low molecular weight

21
Q

In physical adsorption, a gas of (pick the wrong)

A

high critical temperature (this is prolly correct) is adsorbed in preference to a gas of law critical (wrong?) temperature

low volatility is adsorbed in preference to a gas of high volatility

22
Q

Which of the following adsorbents is used to decolorize yellow glycerine?

A

activated carbon

23
Q

When adsorption hysteresis is observed, the desorption equilibrium pressure is

A

always lower than that obtained by adsorption

24
Q

Chemisorption (chemical adsorption) is

A

also called activated adsorption

25
Q

Physical adsorption is

A

accompanied by evolution of heat a reversible phenomenon

26
Q

A unit operation wherein specific components s of a fluid phase (gas or liquid) are preferentially adhered to the surfaces of the solid

A

adsorption

27
Q

The adsorbent used in the purification of hydrocarbon products

A

silica gel

28
Q

The component adsorbed in adsorption operation is called

A

adsorbate

29
Q

A type of adsorption which results in intermolecular forces of attraction between molecules of the solid and the substance adsorbed.

A

physical adsorption