Adsorption Flashcards
concentration of a substance on the surface of a solid or a liquid
adsorption
substance attracted to a surface
absorbate phase
substance to which it is attached
absorbent
factors that determined the amt of gas adsorbed by a solid
- nature of adsorbent and gas na inaabsorbed by a solid
- area of absorbent
- temperature of the gas
- pressure of the gas
Types of adsorption
- physical or van der waal’s adsorption
- chemical or activated adsorption or chemisorption
occurs when the intermolecular
forces of attraction between the fluid molecules and the solid surface are greater than the attractive forces between molecules of the fluid itself.
Physical or Van Der Waal’s Adsorption
Fluid molecules adhere to the surface of the solid adsorbent. The forces responsible for the adsorption are of the same fluid as are involved in the deviation of gases ideal behavior and in liquefaction, i.e. Van der Waal’s forces.
-characterized by low heats of adsorption.
Physical or Van Der Waal’s Adsorption
involves chemical interaction between the adsorbed fluid and the adsorbent solid.
Chemical or Activated Adsorption or Chemisorption
The adsorption is irreversible and it is difficult to separate the adsorbate from the adsorbent. Hence, only physical adsorption tends itself to continuous stage-wise operations.
Chemical or Activated Adsorption or Chemisorption
The ____________________ relates the concentration of the adsorbate in the solution and the adsorbate on the adsorbent at equilibrium at a given temperature.
Freundlich Isotherm
this has binding site where particles come in and there is chemical reaction
chemical adsorption
Freundlich Equation applies to adsorption of solute from
dilute solutions, over a small concentration range
In case of physical adsorption, the difference between heat of adsorption and heat of normal condensation is
equal to the heat of wetting
CO2 can be adsorbed by
heated charcoal
lon exchange process is similar to
adsorption