ADDITIONAL NOTES IN INORG CHEMISTRY Flashcards

1
Q

Artificial Atmospheres

A

Nitrogen, Oxygen, Helium, Carbon dioxide & Nitrous Oxide

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2
Q

GROUP IA: ALKALI METALS

A

•Hydrogen
•Lithium
•Sodium
•Potassium

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3
Q

• not actually a metal
• Inflammable air
• Lightest element

A

Hydrogen

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4
Q

• Uses: Inflating balloons

A

Hydrogen

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5
Q

• Lightest metal

A

Lithium

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6
Q

• Use: heat exchanger in air conditioners

A

Lithium

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7
Q

drug of choice for mania

A

Lithium carbonate (Li₂CO₃)

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8
Q

• most abundant extracellular cation
• responsible for fluid retention

A

Sodium

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9
Q

• diuretic, urinary alkalizer, antacid, alkalinizing agent in Benedict’s
solution

A

Sodium acetate

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10
Q

• “baking soda”
• systemic antacid; carbonating agent

A

• Sodium bicarbonate (NaHCO₃)

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11
Q

• cathartic, urinary acidifier (under sodium)

A

Sodium dihydrogen phosphate (NaH₂PO₄)

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12
Q

• water soluble antioxidant (under sodium)

A

Sodium bisulfite (NaHSO₃)

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13
Q

antacid, carbonating agent (under sodium)

A

Sodium carbonate (Na₂CO₃)

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14
Q

electrolyte replenisher, preservative, condiment (under NA)

A

Sodium chloride

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15
Q

anticoagulant (under Na)

A

Sodium citrate

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16
Q

anticariogenic agent (Na)

A

Sodium fluoride

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17
Q

saponifying agent (Na)

A

• Sodium hydroxide (NaOH)

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18
Q

• oxidizing agent; disinfectant, bleaching agent (Na)

A

• Sodium hypochlorite (NaOCl or NaClO)

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19
Q

expectorant; solubilizer of Iodine (Na)

A

Sodium Iodide

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20
Q

vasodilator; antidote for cyanide poisoning

A

Sodium nitrite

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21
Q

Sodium nitrate (NaNO₃)

A

meat preservative

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22
Q

Sodium sulfate (Na₂SO₄)

A

cathartic

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23
Q

primary standard for Karl Fischer reagent

A

Sodium tartrate (Na₂C₄H₄O₆)

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24
Q

Sodium thiocyanate (NaSCN)

A

• hypotensive agent

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25
Q

treatment of cyanide poisoning.

A

• Sodium thiosulfate (Na₂S₂O₃)

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26
Q

• most abundant intracellular cations
• for muscular contraction

A

Potassium

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27
Q

diuretic, urinary alkalizer, antacid

A

Potassium acetate (C₂H₃KO₂)

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28
Q

antacid, carbonating agent

A

Potassium bicarbonate (KHCO₃)

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29
Q

Potassium bitartrate (KHC₄H₄O₆)

A

laxative

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30
Q

Potassium bromide (KBr)

A

depressant

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31
Q

Potassium carbonate (K₂CO₃)

A

antacid, carbonating agent

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32
Q

ingredient of toothpaste, mouthwashes, gargles

A

Potassium chlorate (KClO₃)

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33
Q

Potassium chloride (KCl)

A

electrolyte replenisher

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34
Q

Potassium citrate (K₃C₆H₅O₇)

A

diuretic, expectorant, diaphoretic

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35
Q

Potassium hydroxide (KOH)

A

• saponifying agent

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36
Q

Potassium iodide (KI)

A

expectorant, solubilizer of iodine

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37
Q

Potassium nitrate (KNO₃)

A

meat preservative

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38
Q

oxidizing agent, antidote for strychnine

A

Potassium permanganate (KMnO₄)

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39
Q

Potassium sodium tartrate

A

• cathartic, sequestering agent/chelating agent

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40
Q

• a mixture of potassium polysulfide and potassium thiosulfate
• ingredient of white lotion

A

Sulfurated Potash

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41
Q

• catalyst in polymerization of resin

A

Cesium (Cs)

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42
Q

• used in density gradient centrifugation (separates proteins)

A

• Cesium chloride

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43
Q

• hypothetical alkali metal
• diuretic, expectorant, anticariogenic, buffer

A

Ammonium

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44
Q

• Ammonium bromide (NH₄Br)

A

• sedative, depressant

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45
Q

• expectorant, respiratory stimulant, antacid, Ingredient of
aromatic ammonia spirit

A

• Ammonium carbonate: (NH₄)₂CO₃

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46
Q

Aromatic ammonia spirit

A

• respiratory stimulant

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47
Q

Ammonium chloride (NH₄Cl)

A

diuretic, expectorant, urinary acidifier

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48
Q

Ammonium iodide (NH₄I)

A

expectorant

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49
Q

GROUP IB: COINAGE METALS

A

•Copper (Cu)
•Silver (Ag)
•Gold (Au)

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50
Q

• only reddish colored metal
• 3rd most malleable metal, 3rd best conductor of electricity
• Protein precipitant

A

Cu (Copper)

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51
Q

• Used in preparation of Benedict’s, Barfoed’s, and Fehlings solution
(test of raduring agents)
• Emetic

A

Copper sulfate (CuSO₄)

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52
Q

• Antidote for phosphorus poisoning
• Component of Bordeaux mixture (an algicide/fungicide in swimming pools)

A

• Copper sulfate (CuSO₄)

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53
Q

Copper acetoarsenite

A

Insecticide

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54
Q
  • 2ND most malleable metal
  • 2nd best conductor of electricity
  • Oligodynamic action
A

SILVER (Ag)

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55
Q

Silver (Ag) Poisoning is called ______.

A

argyria

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56
Q
  • Removal of warts
  • Eyewash for newly born babies of mothers with gonorrhea
A

Silver nitrate

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57
Q

dental protective, Ingredient of Tollen’s reagent

A

Ammoniated silver nitrate (𝐍𝐇𝟑)𝟐 𝐍𝐎𝟑

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58
Q

Silver iodide

A

germicide

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59
Q

Mild silver protein

A

antiseptic for the eyes

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60
Q

Strong Silver Protein

A

antiseptic for the ears, nose and throat

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61
Q

colloidal Silver Protein

A

general germicide

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62
Q

“king of all metals”

A

Gold (Au)

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63
Q
  • Most malleable metal
  • best conductor of electricity
  • Compounds are used for the treatment of rheumatoid arthritis
A

Gold (Au)

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64
Q

GROUP II-A: ALKALINE-EARTH METALS

A

•BERYLLIUM (Be)
•MAGNESIUM (Mg)
•CALCIUM
•STRONTIUM (Sr)
•BARIUM (Ba)
•RADIUM (Ra)

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65
Q
  • Most toxic metal
  • Can cause lung carcinoma, chronic granuloma
A

Beryllium (Be)

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66
Q
  • Lightest of all structurally important metal
  • 2nd most abundant intracellular cation
A

Magnesium (Mg)

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67
Q
  • natural calcium channel blocker
  • also present in chlorophyll -present in Grignard Reagent (R-Mg-X)
A

Magnesium (Mg)

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68
Q

antacid; laxative

A

Magnesium carbonate & Magnesium hydroxide 𝐌𝐠 (𝐎𝐇)𝟐

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69
Q

antacid; component of universal antidote

A

Magnesium oxide (𝐌𝐠𝐎)

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70
Q

antacid (has prolonged effect due to gelatinous consistency of preparation)

A

Magnesium trisilicate 𝟐𝐌𝐠𝐎 ∙ 𝟑𝐒𝐢𝐎𝟑∙ 𝒏𝐇𝟐𝐎

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71
Q

cathartic; anticonvulsant

A

Magnesium sulfate (𝐌𝐠 𝐒𝐎𝟒)

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72
Q

adsorbent, filtering aid, clarifying agent, dusting powder (Mg compound)

A

Hydrated Magnesium silicate

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73
Q

Magnesium citrate 𝐌𝐠𝟑 (𝐂𝟔𝐇𝟓𝐎𝟕)𝟐

A

cathartic

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74
Q
  • 2ND most abundant extracellular cation
  • blood coagulation factor
A

Calcium

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75
Q

sedative (Ca compound)

A

Calcium bromide (𝐂𝐚𝐁𝐫𝟐)

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76
Q
  • “Prepared /Precipitated chalk”
  • antacid; carbonating agent→causes rebound hyperacidity
A

Calcium carbonate (𝐂𝐚𝐂𝐎𝟑)

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77
Q
  • “Muriate of Lime”
  • electrolyte replenisher
A

Calcium chloride

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78
Q
  • Milk of Lime, Slaked Lime, Calcium hydrate
  • saponifying agent
A

Calcium hydroxide [ 𝐂𝐚 (𝐎𝐇𝟐)]

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79
Q
  • Lime, Quick Lime; Calx
  • preparation of various insecticide; Bordaux mixture
A

Calcium oxide 𝐂𝐚𝐎

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80
Q
  • “bone ash”
  • antacid
A

Calcium phosphate [ 𝐂𝐚 𝟑 (𝐏𝐎𝟒)𝟐 ]

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81
Q
  • bleaching agent, disinfectant (Ca compound)
A

Calcium hypochlorite 𝐂𝐚 (𝐂𝐥𝐎)𝟐

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82
Q
  • Plaster of Paris
  • Gypsum (mineral source)
  • Terra Alba (white cement)
  • preparation of surgical casts; dentifrice
A

Calcium sulfate

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83
Q

Calcium sulfate hydrated→ _______

A

𝐂𝐚𝐒𝐨𝟒∙ 𝟏/𝟐 𝐇𝟐𝐎

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84
Q
  • flame test: crimson color
  • salts are used in red pyrotechnics
A

Strontium (Sr)

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85
Q
  • temperature desensitizing agents (Sr compound)
A

Strontium chloride (Sensodyne)

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86
Q
  • Flame test: yellow /apple grem color
  • salts are used in green pyrotechnics
A

BARIUM (Ba)

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87
Q
  • radiopaque substance for GIT imaging; contrast medium
A

Barium sulfate

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88
Q
  • carbon dioxide absorbent
A

Barium hydroxide

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89
Q
  • radioactive substance discovered by Marie Cury
A

RADIUM (Ra)

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90
Q

• aka Zinc Family
• melting points
• volatilized at RT

A

GROUP IIB: VOLATILE METALS

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91
Q
  • metal present in insulin
  • as container for batteries and dry cells
A

ZINC (Zn)

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92
Q
  • protective coating of galvanized iron→steel coated with zinc
  • astringent, antiseptic, antiperspirant, protectant
A

ZINC (Zn)

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93
Q

steel coated with zinc

A

galvanized iron

94
Q
  • antiseptic found in mouthwashes, topical protectant, dentin desensitizer
A

Zinc Chloride

95
Q
  • mild antiseptic, astringent, topical protectant
A

Zinc oxide

96
Q
  • antiseptic (Zr compound)
A

Zinc peroxide (𝐙𝐧𝐎𝟐)

97
Q
  • While vitriol
  • emetic; astringent; ingredient of white lotion
A

Zinc sulfate

98
Q
  • active component of white lotion
  • scabicidal agents
    sulfurated potash + Zinc sulfate
  • antiseptic and protectant
A

Zinc sulfide

99
Q
  • natural calamine
  • topical protectant; anti-itch
    prepared calamine→ 𝐙𝐧𝐎 ∙ 𝐅𝐞𝟐𝐎𝟑
    ex. Caladryl 
A

Hydrated Zinc Silicate 𝐙𝐧𝟐 𝐒𝐢𝐎𝟒∙ 𝐇𝟐𝐎

100
Q
  • dental protective; dentifrice
  • Zinc oxide + clove oil
A

Zinc-eugenol cement

101
Q
  • caused “itai-itai” poisoning
A

CADMIUM (Cd)

102
Q
  • emetic, treatment of tinea infections
A

Cadmium chloride

103
Q
  • antiseborrheic agent
  • only yellow sulfide
A

Cadmium sulfide

104
Q
  • ophthalmic antiseptic (Cd compound)
A

Cadmium sulfate

105
Q
  • industrial uses: manufacture of thermometers, formation of amalgams
  • caused “Minamata” poisoning
  • pharmacologic actions: diuretic, antiseptic, antisyphilis, cathartic, parasiticide, fungicide
A

Mercury (Hg)

106
Q
  • active component of Lyna→ Menna
  • cathartic, antiseptic
A

Mercurous chloride -Calomel (𝐇𝐠𝟐𝐂𝐥𝟐)

107
Q
  • Corrosive Sublimate
  • disinfectant
A

Mercuric chloride (𝐇𝐠𝐂𝐥𝟐)

108
Q
  • anti-syphilis
A

Mercurous iodide (𝐇𝐠𝐈)

109
Q
  • antiseptic; ingredient of Mayer’s reagent (most sensitive)
A

Potassium mercuric iodide 𝐊𝟐𝐇𝐠𝐈𝟒

110
Q
  • “White Precipitate”
  • topical anti-infective
A

Ammoniated Mercury (𝐇𝐠 𝐍𝐇𝟐𝐂𝐥)

111
Q
  • ” Yellow precipitate”
  • ophthalmic antiseptic
A

Mercuric oxide (𝐇𝐠𝐎)

112
Q

GROUP IIIA: BORON FAMILY

A

•BORON (B)
•ALUMINUM
•GALLIUM (Ga)
•THALLIUM (Tl)

113
Q
  • used in vulcanizing rubber
A

Boron (B)

114
Q
  • eyewash (2% w/v)
  • buffer component
A

Boric Acid (𝐂𝟑𝐁𝐎𝟑)→ Sal sedativum

115
Q
  • antiseptic; eyewash; wet dressing for wounds;
A

Sodium tetraborate (𝐍𝐚𝟐𝐁𝟒𝐎𝟕)

116
Q
  • most abundant metal
  • 3rd most abundant element
  • Pharmacologic actions: constipation, astringent, antiperspirant, deodorant; thin Al foil is
    used to treat burns
A

ALUMINUM

117
Q

Aluminum poisoning is called _______.

A

Shaver’s disease

118
Q
  • Astringent, antiseptic, antiperspirant, deodorant
A

Aluminum chloride 𝐀𝐥𝐂𝐥𝟑∙ 𝟔𝐇𝟐𝐎

119
Q

antacid→interferes with phosphate absorption
ex. Amphogel 

A

Aluminum hydroxide 𝐀𝐥(𝐎𝐇)𝟑

120
Q
  • antacid →does not interfere phosphate absorption
    ex. Phosphagel
A

Aluminum phosphate 𝐀𝐥𝐏𝐎𝟒

121
Q
  • treatment of phosphatic calculi (elimination of 𝐏𝐎𝟒 via fecal route)
A

Aluminum carbonate 𝐀𝐥𝟐(𝐂𝐎𝟑)𝟑

122
Q
  • astringent, antiperspirant, deodorant (Al compound)
A

Alum 𝑨𝒍𝑲 (𝐒𝐎𝟒)𝟐 𝒐𝒓 𝐀𝐥𝐍𝐇𝟒(𝐒𝐎𝟒)𝟐

123
Q
  • treatment of silicosis
A

Aluminum oxide 𝐀𝐥𝟐𝐎𝟑 → aka Alumina

124
Q

Aluminum silicates:

A

•Kaolin
•Bentonite
•Pumice

125
Q
  • native hydrated Al silicate
  • adsorbent - tx of mild diarrhea
A

Kaolin

126
Q

aka China Clay

A

Kaolin

127
Q
  • suspending agent
  • native colloidal hydrated Al silicate
  • suspending agent
A

Bentonite

128
Q

Bentonite → Mineral soap/ Soap clay preparation: _________

A

Bentonite magma (5)

129
Q
  • complex silicate of Al, Na and K → volcanic origin
  • dental abrasive
A

Pumice

130
Q
  • substitute for mercury in the manufacture of arc lamps
A

Gallium (Ga)

131
Q
  • for the treatment of cancer-related hypercalcemia
A

Gallium nitrate 𝐆𝐚(𝐍𝐎𝟑)𝟑

132
Q
  • rodenticide
  • poisoning causes green tongue and alopecia
A

THALLIUM (Tl)

133
Q

GROUP IVA: CARBON FAMILY

A

•CARBON
•SILICON (Si)
•TIN (Sn)
•LEAD (Pb)

134
Q
  • nonmetal
  • can form multiple bonds with itself (catenation/ Chain formation)
A

Carbon (C)

135
Q
  • adsorbent, component of universal antidote
A

activated charcoal

136
Q
  • respiratory stimulant
  • treatment of persistent hiccups
  • dry ice: treatment of acne, corns, calluses, moles, warts, eczema
A

Carbon dioxide

137
Q
  • antacids, carbonating agents (C compounds)
A

Carbonates/Bicarbonates

138
Q
  • toxic gas, causes hypoxia
A

Carbon monoxide

139
Q
  • 2ND most abundant element
  • Forms inert oxide called silica which causes silicosis
A

Silicon (Si)

140
Q

prepared by fusing a base such as sodium carbonate and pure silica

A

Glass

141
Q

Appearance and characteristics of glasses can be modified by the addition of:

A
  1. MnO2
  2. boron/borates
  3. potassium
  4. lead
142
Q
  • Adsorbent, clarifying agent, filtering aid
A

Silicon dioxide

143
Q
  • Antifoaming agent; anti-flatulent
A

Simethicone

144
Q
  • Used in manufacture of cans, household utensils
A

TIN (Sn)

145
Q
  • Anticariogenic agent
A

Stannous fluoride 𝐒𝐧𝐒𝟐

146
Q
  • Germicide against Staphylococcal infection
A

Stannic oxide 𝐒𝐧𝐎𝟐

147
Q
  • Germicide against Staphylococcal infection
A

Stannic oxide 𝐒𝐧𝐎𝟐

148
Q

Lead (Pb) Poisoning is called _____.

A

plumbism

149
Q
  • Astringent, ingredient of lead subacetate solution
A

Lead acetate

150
Q
  • astringent; antiseptic (Pb compounds)
A

Lead subacetate

151
Q

GROUP IVB: TITANIUM FAMILY

A

•TITANIUM (Ti)
•ZIRCONIUM (Zr)

152
Q
  • powerful reducing agent
A

Titanium (Ti)

153
Q
  • solar ray protectant
  • opacifying agent
A

Titanium dioxide

154
Q
  • used as deodorant and antiperspirant
  • causes granuloma formation
A

ZIRCONIUM (Zr)

155
Q

GROUP VA: NITROGEN FAMILY

A

•NITROGEN (N)
•PHOSPHORUS (P)
•ARSENIC
•ANTIMONY
•BISMUTH

156
Q
  • inert atmosphere for readily oxidizable pharmaceuticals
  • liquid nitrogen-refrigerant
A

Nitrogen (N)

157
Q
  • meat preservative (N compounds)
A

Nitrates/Nitrites

158
Q
  • inhalatory anesthetic
A

Nitrous oxide

159
Q

2 forms of Phosphorus (P)

A

• Red
• White/yellow

160
Q
  • Antacids; cathartics (P compounds)
A

Phosphates

161
Q
  • Component of Salvarsan
A

Arsenic

162
Q
  • Used to prepare insecticides such as:
    1. Paris green
    2. Fowler’s solution -K arsenite
    3. Donovan’s solution- 1% mercuric iodide
    arsenic O3
A

Arsenic trioxide

163
Q
  • Expectorant, emetic, anthelmintic
A

Antimony

164
Q
  • Expectorant, emetic, treatment of schistosomiasis
A

Antimony potassium tartrate

165
Q

Astringent, antiseptic, internal protective → mng. of gastrin/ peptic ulcers

A

BISMUTH

166
Q

GROUP VB

A

•Tantalum

167
Q
  • Not affected by body fluids
  • Used for the surgical repair of bones, nerves and tissues (implants)
A

TANTALUM (Ta)

168
Q

GROUP VIA: OXYGEN FAMILY

A

•OXYGEN
•SULFUR (S)
•SELENIUM (Se)

169
Q
  • Most abundant element
A

Oxygen

170
Q

Three allotropes of Oxygen:

A
  1. Nascent oxygen 𝐎
  2. Ozone 𝐎𝟐
  3. Atmospheric/molecular oxygen 𝐎𝟑
171
Q

Conditions based on oxygen requirement

A
  1. Anoxic
  2. Anemic
  3. Stagnant
  4. Histotoxic
172
Q

Brimstone

A

Sulfur (S)

173
Q

2 forms of Sulfur:

A
  1. Precipitated sulfur
  2. Sublimed sulfur
174
Q

Precipitated sulfur - _______ -> used in ointments and lotions

A

Milk of sulfur

175
Q

Sublimed sulfur- _______ → used as cathartic

A

Flowers of sulfur

176
Q
  • Essential trace element
  • Synergistic with Vit E as antioxidant
A

SELENIUM (Se)

177
Q
  • Antiseborrheic agent
A

Selenium sulfide (𝐒𝐞𝐒𝟐)

178
Q

GROUP VIB

A

•CHROMIUM (Cr)
•MOLYBDENUM (Mo)
•URANIUM (U)

179
Q
  • Essential trace element- similar fxn of insulin
  • Glucose tolerance factor
A

Chromium

180
Q
  • Oxidizing agent (Cr compounds)
A

Potassium dichromate (𝐊𝟐𝐂𝐫𝟐𝐎𝟕)

181
Q
  • essential trace element
  • cofactor of flavin dependent enzymes
  • involved in bacterial fixing of atmospheric nitrogen
A

MOLYBDENUM (Mo)

182
Q
  • radioactive element discovered by Becquerel
  • used in manufacture of atomic bombs
    1 Bq= 1 disintegration per second
    (1 Bq= 1 dps)
A

URANIUM (U)

183
Q

GROUP VIIA: HALOGEN FAMILY

A

•FLUORINE (F)
•CHLORINE (CI)
•BROMINE (Br)
•IODINE (I)
•ASTATINE (At)
•MANGANESE (Mn)
•TECHNETIUM (Tc)

184
Q
  • most electronegative element
  • strongest oxidizing agent
A

FLUORINE (F)

185
Q
  • anticariogenic agents (F)
A

Fluorides

186
Q
  • refrigerant, aerosol propellant
A

Dichlorodifluoromethane (𝐂𝐂𝐥𝟐𝐅𝟐)– aka Freon

187
Q
  • “Dephlogisticated Muriatic Acid”
  • chloride - most abundant extracellular anion
  • Important compounds: chlorides and hypochlor
A

CHLORINE (CI)

188
Q
  • toilet bowl cleaner (muriatic acid)
  • diluted HCI- treatment of achlorhydria
    (absence of acid in stomach)
    10% w/v (except diluted acetic acid 6%)
A

Hydrochloric acid

189
Q
  • dark reddish brown fuming liquid with a suffocating odor
A

BROMINE (Br)

190
Q

Bromine poisoning is called _____.

A

bromism

191
Q
  • element present in thyroid gland
  • elemental iodine preparations:
    1. Strong iodine solution
    Lugols solution- tx- hyperthyroidism
    2. Iodine Tincture
    3. Povidone-iodine
A

Iodine

192
Q
  • tx- hyperthyroidism
A

Lugols solution

193
Q
  • Synthetic, radioactive and metallic halogen
A

ASTATINE (At)

194
Q

GROUP VIIB

A

•MANGANESE (Mn)
•TECHNETIUM (Tc)

195
Q
  • Essential trace element
  • Cofactor involved in protein synthesis, phosphorylation, and fatty and cholesterol
    syntheses
A

Manganese (Mg)

196
Q
  • First element produced artificially
  • Used in preparation of radiopharmaceuticals (Tc-99)
A

TECHNETIUM (Tc)

197
Q
  • aka “Group Zero
A

GROUP VIIIA: INERT/NOBLE GASES

198
Q
  • 2nd lightest gas
  • Inhalation of pure helium produces a Donald Duck or Chipmunk-like sound
  • Component of artificial air
A

Helium (He)

199
Q
  • Used for advertising purposes
A

Neon (Ne)

200
Q
  • Most abundant noble gas
  • as substitute for nitrogen as inert atmosphere
A

Argon (Ar)

201
Q
  • least abundant noble gas
  • anesthetic
A

Krypton (Kr)

202
Q
  • anesthetic
A

Xenon (Xe)

203
Q
  • synthetic and radioactive noble gas
  • treatment of cancer
A

Radon (Rn)

204
Q

GROUP VIIIB: TRIADS

A

First triad: Fe, Co, Ni
Second triad: Rh, Ru, Pd
Third triad: Os, Ir, Pt

205
Q

First triad:

A

Fe, Co, Ni

206
Q

Second triad:

A

Rh, Ru, Pd

207
Q

Third triad:

A

Os, Ir, Pt

208
Q
  • essential trace element (in the first triad)
A

Iron (Fe)

209
Q
  • hematinic agent
  • most commonly used
  • GI imitant
  • Green Vitriol
A

Ferrous sulfate (𝐅𝐞𝐒𝐨𝟒)

210
Q
  • hematinic agent
  • less gastric irritating
A

Ferrous gluconate - Fergon

211
Q
  • hematinic agent
  • more stable than ferrous sulfate
A

Ferrous fumarate- Toleron

212
Q

→ Ferruginous pills; Chalybeate pills, Blaud’s pills
- hematinic agent

A

Ferrous carbonate (𝐅𝐞𝐂𝐎𝟑)

213
Q
  • “Basham’s mixture”
  • astringent
  • styptic-stop bleeding of small wounds
A

Iron + ammonium acetate 𝐅𝐞 + 𝐍𝐇𝟒 𝐂𝐇𝟑 𝐂𝐎𝐎

214
Q
  • astringent and styptic
  • test for tannins and phenols
A

Ferric chloride (𝐅𝐞𝐂𝐥𝟑)

215
Q

→ Prussian blue
- blue print dye

A

Ferric ferrocyanide 𝐅𝐞𝟒 [𝐅𝐞 (𝐂𝐍𝟔)]𝟑

216
Q

→ Turnbull’s blue
- blue print dye

A

Ferro ferricyanide 𝐅𝐞𝟑 [𝐅𝐞 (𝐂𝐍𝟔)]𝟐

217
Q
  • essential in the development of erythrocytes and hemoglobin
  • metal present in Vit B12
  • used in manufacture beer- enhance foaming quality of beer
A

Cobalt (Co)

218
Q

→ “Lover’s ink/ Sympathetic ink”
- indicator in silica gel beads
color: blue, pink, white (very light pink)
Blue- anhydrous
Pink- hydrated

A

Cobalt chloride (𝐂𝐨𝐂𝐥𝟐)

219
Q

“Old Nick’s Copper”

A

Nickel (Nickel)

220
Q
  • found in fossil fuel combustion
  • metal in fancy jewelries
  • causes “Nickel itch”→ contact dermatitis
A

Nickel (Ni)

221
Q

causes contact dermatitis

A

Nickel (Ni)

222
Q

used as parasiticides (Ni compounds)

A
  • 𝐍𝐢𝐂𝐎𝟑
  • 𝐍𝐢𝐒𝐎𝟒
223
Q
  • heaviest and densest metal
A

OSMIUM (Os)

224
Q
  • staining of specimen
A

Osmic acid (𝐎𝐬𝐎𝟒)

225
Q
  • catalyst
  • used in making crucibles
  • more expensive thon gold.
  • for E microscopy
A

Platinum (Pt)

226
Q

Cisplatin (cis-diamminedichloroplatinum)

A
  • treatment of prostate cancer
227
Q
  • not effective
A

Transplatin

228
Q
  • used as anticancer agent
A

Carboplatin

229
Q
  • less toxic than cisplatin
A

Carboplatin

230
Q
  • catalyst→ in catalytic hydrogenation
A

PALADIUM (Pd)