Acids, bases, energy levels and chem reactions WK 1 Flashcards
Differ between acids and bases
Acid :proton donor (release H+)
Base: proton acceptor(accept H+)
Define pH. When is it acidic, acidic, neutral
measure derived from molarity of H+ on logarithmic scale
-pH 7=neutral (H=OH)
-pH of less than 7=acidic
-pH more than 7=basic
Describe ratio of change between pH and H+ conc
change in one number on Ph scale=10 fold change in H+ conc
e.g. pH 4 is 10x more acidic than pH 5
Describe buffers
chemical solution that resists changes in pH
How do H atoms become H+ ions
lose and electron
When is something extremely reactive
can break chem bonds and disrupt cell function
Define energy
capacity to do work
-all body activities are forms of work
Define chem energy, potential energy, kinetic, activation and free energy
chem: potential energy in molecular bond
potential: energy stored in an object (not currently working)
free: potential energy available in system to do work
kinetic: energy of motion, doing work
activation: energy required to start chemical reaction
Differ between exergonic and endergonic
Energy releasing process-exergonic
Energy conserving process endergonic
Define chem reaction and chem equation
reaction: process in which covalent or ionic bond is formed or broken
equation: symbolises course of a chemical reaction
Describe/define the three classes of chemical reactions. Provide e.g. equation structure for each
synthesis: two or more smaller molecules combine to form larger
(A + B—> AB)
decomposition: large molecule breaks down into two or more smaller ones
(AB—> A + B)
exchange: two molecules exchange atoms or group of atoms
(AB+CD–>ABCD–AC + BD)
Define metabolism
all chem reactions in body
Describe/define catabolism
releasing energy (exergonic) decomposition reactions
-break covalent bonds
-produce smaller molecules
Describe/define anabolism
energy-storing (endergonic) synthesis reactions
-requires energy input
-productions of protein or fat
What is the connection between anabolism and catabolism
inseparably linked.
-anabolism is driven by energy released by catabolism
Describe/define oxidation reactions
chem reaction where molecule gives up e and release energy
-molecule oxidised in process
-e acceptor (base) molecule is oxidising agent (reduced)
Describe/define reduction reactions
chem reaction where molecule gains e and energy
-molecule reduced when accepting e
-molecule donating e (acid) is reducing agent (oxidised)
Describe what is meant by oxidation-reduction reactions
oxidation of one molecule accompanied always by reduction of another
-e are transferred as H atoms
-reactions catalysed by enzymes (H removed-dehydrogenases, were O added-oxidases)
Describe the 4 types of chem reactions
Decomposition=catabolism(release energy)
Break bonds between large complex molecules=smaller fragments (absorbed)
Hydrolysis=Decomp. involving water, components of water molecule join new fragments
Synthesis=anabolism (requires energy)
Assembles smaller into larger molecules
Dehydration synthesis= condensation-complex molecules formed by removal of H2O
How are H atoms removed from metabolic intermediates
in pairs
-2x proteins and 2xe-
-transfer to co-enzymes (become temporary carriers of energy extracted)
-NAD^+ (nicotinamide adenine dinucleotide, derived from niacin (B vitamin)
NAD^++2 H→NADH+H^+
-FAD (flavin adenine dinucleotide, derived from riboflavin)
FAD+2 H→FADH_2