acids and bases Flashcards

1
Q

what are the qualities of acid

A

Acids have a pH below 7
They are corrosive and sour tasting
In acidic conditions blue litmus paper and methyl orange turns red
Acids are proton donors as they ionize in solution producing protons, H+ ions
These H+ ions make the aqueous solution acidic

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2
Q

what are the qualities of bases

A

Bases have pH values of above 7
They taste bitter and chalky
Bases turn litmus paper blue and methyl orange yellow
A base which is water-soluble is referred to as an alkali
They are metal hydroxides
Bases are usually oxides or hydroxides of metals, except for ammonia
Bases (alkalis) are proton acceptors as they ionize in solution producing OH– ions which can accept protons
These OH– ions make the aqueous solution alkaline

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3
Q

formula of stoichometry for neutralisation reaction

A

Ma Va = Mb Vb

M =molarity/concentration
V= volume in cm3
a=acid
b=base

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4
Q

what are the steps in analytical titration

A

Measure amount of unknown concentration solution and place in beaker
Add indicator
Titrate using known concentration until the endpoint is reached
Calculate the concentration of the solution in the beaker

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5
Q

methods to prepare salts

A

Titration
Titration of acid and alkali to make salt and water
The salt is a soluble salt so you have to crystallise it
The Alkali is the solution

Evaporation method
Needs excess addition of insoluble base/metal with acid
Need to filter then crystallise it
Precipitation
Mixing two solutions of soluble salt to make an insoluble salt
Need to filter then wash/dry it

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6
Q

solubility rule

A

All K+, Na+, NH4+ = Soluble​
All Ethanoate, CH3COO- & Nitrate, NO3- = Soluble​
All Carbonate, CO32- = Insoluble, except K+, Na+, NH4+​
All Halides (Cl-,Br-,I-)= Soluble, except Ag+, Pb2+
All SO42- = Soluble, except Pb2+, Ba2+, Ca2+

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7
Q

ways to make soluble salts

A
  • acid+alkali titration

- acid+excess insoluble solid (reactive metal, base or carbonate)

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8
Q

ways to make insoluble salts

A

This involves mixing solutions of two soluble salts that between them contain the ions that make up the insoluble salt. It is made by two methods

  • direct combination
  • precipitation
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9
Q

how to make a sulfate

A

use sulfuric acid

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10
Q

how to make a chloride

A

use hydrochloric acid

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11
Q

what is a strong acid/base

A

Strong acids and bases ionize completely in water, producing solutions of very low pH for an acid or very high pH for a base

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12
Q

what is a weak acid/base

A

Weak acids and bases partially ionize in water and produce pH values which are closer to the middle of the pH scale

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13
Q

what is example of strong acids

A

Strong acids include HCl and H2SO4 and strong bases include the Group I hydroxides

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14
Q

what is an example of weak acids

A

Weak acids include organic acids such as ethanoic acid, CH3COOH (aectic acid) and weak bases include aqueous ammonia

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15
Q

equilibrium in weak acids and alkalis

A

For both weak acids and bases, there is usually an equilibrium set-up between the molecules and their ions once they have been added to water
Example of a weak acid: propanoic acid
CH3CH2COOH ⇌ H+ + CH3CH2COO-
Example for a weak base: aqueous ammonia
NH3 + H2O ⇌ NH4+ + OH-
In both cases the equilibrium lies to the left, indicating a high concentration of intact acid / base molecules, with a low concentration of ions in solution

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16
Q

acid + metal

A

Acids react with metals to form salt and hydrogen

17
Q

acid + base

A

Acids react with bases to form salt and water

18
Q

acid + carbonate

A

Acids react with carbonates to form salt, water and carbon dioxide

19
Q

bases + ammonium salt

A

Bases react with ammonium salts to form salt, water and ammonia

20
Q

what are some indicators

A
Universal indicator is a mixture of indicators. It is useful because it shows a range of colours from pH 1–14.​
pH meter
Direct distinction between acid and base
Litmus paper
Direct distinction between acid and base
Universal Indicator
DIfferent shades for each pH
21
Q

what is pH + formula

A

Stands for potential of hydrogen

Formula is ㏒10(value of mol)

22
Q

what are oxides

A

An oxide is a compound of oxygen and another element

23
Q

what are the four groups of oxides

A

acidic oxides
basic oxides
amphoteric oxides
neutral oxides

24
Q

properties of acidic oxides

A

Acidic oxides are oxides of non-metals (noble gases don’t form acidic oxides)
Acidic oxides are often gases at room temperature
Acidic oxides react with water to form acidic solutions
E.g. sulfur trioxide + water -> sulfuric acid (so3+h20-> H2SO4)
Acidic oxides react with bases and alkalis to produce salts and water
E.g carbon dioxide + sodium hydroxide -> sodium carbonate + water (CO2+2NaOH -> Na2CO3 + H2O)

25
Q

properties of basic oxides

A

Basic oxides are oxides of metals, with exception of ammonia (non-
metal base)
Basic oxides are often solids at room temperature
Most basic oxides are insoluble at room temperature
Basic oxides react with acids to produce salt and water
This is known as a neutralisation reaction
E.g magnesium oxide + hydrochloric acid -> magnesium chloride + water (MgO + 2HCl -> MgCl2 + H2O)
When a metal oxide reacts with an acid, the atoms are rearranged

26
Q

properties of amphoteric oxides

A

Amphoteric oxides are oxides of metals
Some examples of metals that form amphoteric oxides are aluminum, germanium and zinc
They can behave as acidic oxides or basic oxides
They react with acids and alkalis to produce salts
E.g aluminium oxide + hydrochloric acid -> aluminium chloride + water
E.g aluminium oxide + sodium hydroxide -> sodium illuminate + water

27
Q

properties of neutral oxides

A

Neutral oxides are non-metals that form oxides that show neither basic nor acidic properties
They are insoluble in water

28
Q

what are the neutral oxides?

A
  • water
  • carbon monoxide
  • nitric oxide/nitrogen monoxide