Acids and Bases Flashcards

1
Q

What is a Brønsted-Lowry acid?

A

a species that can donate a proton

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2
Q

What is a Brønsted-Lowry base?

A

a species that can accept a proton

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3
Q

What is the formula for pH?

A

pH = - log10[H+]

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4
Q

What is the equation for concentration of H+ ions if the pH is known?

A

[H+] = 10^(-pH)

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5
Q

Is the forward reaction in the equilibrium of water endothermic or exothermic?

A

endothermic

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6
Q

Does water become more or less acidic as temperature increases?

A

more acidic as more H+ ions are produced

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7
Q

What is the equilibrium dissociation constant for?

A

weak acids and bases

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8
Q

What is the equilibrium dissociation constant (Ka)?

A

Ka = [H+][A-]/[HA]

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9
Q

If HA is in excess, how do you find pH?

A

Use [HA] and [A-] along with Ka to find [H+], then pH

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10
Q

If [A-] is in excess, how do you find pH?

A

Use Kw to find [H+] then pH

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11
Q

If HA = A-, how do you find pH?

A

pKa is equal to pH, therefore find pKa

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12
Q

What is the definition of a strong acid?

A

An acid that completely dissociates to its ions when in solution with pH 0-1.

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13
Q

What is the definition of a weak acid?

A

An acid that only partially dissociates when in solution with pH 3-5.

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14
Q

What is the definition of a strong base?

A

A base that completely dissociates to ions when in solution with pH 12-14.

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15
Q

What is the definition of a weak base?

A

A base that only partially dissociates when in solution with pH 9-11.

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16
Q

Give some examples of weak acids

A

Most organic acids (e.g. ethanoic acid), HCN (hydrocyanic acid), H2S (hydrogen sulfide) and H2CO3 (carbonic acid)

17
Q

Give some examples of strong acids

A

Hydrochloric, nitric and sulfuric acid

18
Q

On a pH titration curve, how do we identify the neutralisation or equivalence point?

A

the large vertical section and the equivalence point is approximately in the middle of the large vertical section

19
Q

How do we investigate the neutralisation point?

A

alkali is slowly added to an acid and the pH measured with a pH probe or vice versa

20
Q

How do we make a titration curve more accurate?

A

add smaller volumes of either acid or alkali

21
Q

What is the neutralisation point around for a strong acid and strong base reaction?

A

pH 7

22
Q

What is the neutralisation point around for a strong acid and a weak base reaction?

A

less than pH 7 (more acidic)

23
Q

What is the neutralisation point around for a weak acid and a strong base reaction?

A

more than pH 7 (more basic)

24
Q

What is the neutralisation point around for a weak acid and a weak base reaction?

A

normally pH 7 but hard to determine

25
Q

Why do specific indicators have to be used for specific reactions?

A

they can only indicate a pH change within a certain range

26
Q

When is methyl orange used?

A

for reactions with a more acidic neutralisation point

27
Q

What is the colour change for methyl orange?

A

orange in acids and turns yellow at the neutralisation point

28
Q

When is phenolphthalein used?

A

for reactions with a more basic neutralisation point

29
Q

What is the colour change for phenolphthalein?

A

pink in alkalis and turns colourless at the neutralisation point

30
Q

What do acidic buffer solutions contain?

A

a weak acid and the salt of that weak acid

31
Q

What do basic buffer solutions contain?

A

a weak base and the salt of that weak base

32
Q

What is the definition of a buffer solution?

A

a solution which is able to resist changes in pH when small volumes of acid or base are added