Acids and bases Flashcards

1
Q

Acid + Metal –>

A

Salt + Hydrogen

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2
Q

Acid + Metal Oxide –>

A

Salt + Water

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3
Q

Acid + Metal Hydroxide

A

Salt + Water

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4
Q

Acid + Metal carbonate

A

Salt + CO2 + H2O

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5
Q

Define an acid

A

Proton donor

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6
Q

Define a base

A

proton acceptor

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7
Q

What does amphoteric mean?

A

Water can act as either an acid or a base

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8
Q

How to calculate pH

A

-log[H+]

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9
Q

How to calculate [H+] using pH

A

10^-pH

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10
Q

Key points for the pH scale

A

The smaller the pH, the greater the concentration of H+ ions. A differnce of 1 on the scale means a differnce in x10 of [H+]

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11
Q

Define a strong acid

A

Fully dissociates

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12
Q

What does Ka stand for

A

equilibrium constant in terms of acid dissoiation

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13
Q

Ka equation

A

products over reactants

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14
Q

What is the differnce between monoprotic, diprotic and triprotic

A

Te amount of [H+] ions it contains
x1
x2
x3

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15
Q

Define a weak acid

A

Only partially dissociates

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16
Q

Ka for weak acid

A

[H+][A-]/[HA]

17
Q

What type of acid is a craboxyllic acid

A

weak

18
Q

H+ using Ka

A

(square root)Ka[HA]

19
Q

pKa equation

A

-log[KA]

20
Q

Ka using pKa

A

10^-pKa

21
Q

Kw expression

A

[H+][OH-]

22
Q

H+ using Kw

A

Square root of Kw

23
Q

PH changes with temperature

A

At temp higher than 298K, equilibrium shifts to the right in the endothermic direction to oppose change. [H+] increases. However does not mean it goes more acidic as [H+]=[OH]-

24
Q

Calculating pH

A
25
Q

State why calibrating a pH meter just before it is used improves the accuracy of the pH measurement

A

After storage, it will not provide the right reading

26
Q

describe how you would obtain the pH curve for the titration

A

measure pH of acid, add alkali, stir, measure pH after each addition- repeat until in excess

27
Q

suggest why the conc of NaOH in a solution slowly decreased when left open in air

A

Reacts with Co2 in the air

28
Q

Explain why the temp rise is less

A

same amount of Q distributed over a larger volume

29
Q

pH of magnesium hydroxide compared to calcium

A

lower- Mg is less soluble

30
Q

Draw the displayed formula of H2SO4

A
31
Q

explain why H2O is not shown in the Kw expression

A

[H2O] is constant

32
Q

suggest why the pH probe is washed with distilled water between each measurement

A

to reduce contamination

33
Q

explain why the volume of NaOH added between each pH is smaller as the end point is approached

A

to avoid missing endpoint

34
Q

suggest a suitable piece of apparatus that could be used to measure out the sodium hydroxide solution, explain why this apparatus is more suitable than a pipette

A

burette- can deliver variable volumes

35
Q

why would the end point of the graph is difficult to judge accurately

A

the change in pH is gradual, would change colour over a range of volumes

36
Q

a practical procedure to obtain data that a graph could be plotted from

A

place in a fixed volume of alkali in a flask or beaker. add acid in small portions from burette, stir and use pH meter to record pH after each decision

36
Q

suggest how the practical procedure could be refined

A

repeat with indicator- select the indicator that changes colour rapidly from pH 7 to 4